Publication:
Solvents effect on infrared spectra of trimethyl phosphate in organic solvents

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dc.contributor.authorTekin, Nalan
dc.contributor.buuauthorCebe, Mustafa
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.scopusid6506210722
dc.date.accessioned2022-03-25T13:26:20Z
dc.date.available2022-03-25T13:26:20Z
dc.date.issued2004-10-18
dc.description.abstractInfrared spectroscopy studies of trimethyl phosphate (TMP) in 17 different pure organic solvents were undertaken to investigate the solvent-solute interactions and to correlate solvent properties such as the Kirkwood-Bauer-Magat (KBM) equation, the solvent acceptor number (AN) and the linear solvation energy relationships (LSER), respectively, with the infrared band shift. Poor correlation between dielectric constants and the frequencies showed that the KBM relationship was unsuitable for the investigated molecules. These frequencies exhibited a better correlation with the LSER than the solvent AN.
dc.identifier.citationTekin, N. ve Cebe, M. (2004). “Solvents effect on infrared spectra of trimethyl phosphate in organic solvents”. Vibrational Spectroscopy, 36(1), 129-133.
dc.identifier.endpage133
dc.identifier.issn0924-2031
dc.identifier.issue1
dc.identifier.scopus2-s2.0-7444224772
dc.identifier.startpage129
dc.identifier.urihttps://doi.org/10.1016/j.vibspec.2004.05.001
dc.identifier.urihttp://hdl.handle.net/11452/25361
dc.identifier.volume36
dc.identifier.wos000225111400015
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherElsevier
dc.relation.collaborationYurt içi
dc.relation.journalVibrational Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemistry
dc.subjectSpectroscopy
dc.subjectInfrared spectroscopy
dc.subjectLinear solvation energy relationships
dc.subjectSolvent effects
dc.subjectTrimethyl phosphate
dc.subjectSolvation energy relationships
dc.subjectVibrational frequency-shifts
dc.subjectPi-star
dc.subjectIR
dc.subjectSystems
dc.subjectNMR
dc.subjectHydrogen
dc.subjectEquation
dc.subjectAcetone
dc.subjectSolutes
dc.subjectAlkalinity
dc.subjectHydroxylation
dc.subjectMolecular vibrations
dc.subjectPermittivity
dc.subjectPhosphates
dc.subjectElectronic polarization
dc.subjectOrganic compounds
dc.subject.scopusFourier Transform Infrared Spectroscopy; Continuum Model; Solvation
dc.subject.wosChemistry, analytical
dc.subject.wosChemistry, physical
dc.subject.wosSpectroscopy
dc.titleSolvents effect on infrared spectra of trimethyl phosphate in organic solvents
dc.typeArticle
dc.wos.quartileQ4
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

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