Yayın: Solvents effect on infrared spectra of trimethyl phosphate in organic solvents
Tarih
Kurum Yazarları
Cebe, Mustafa
Yazarlar
Tekin, Nalan
Danışman
Dil
Türü
Yayıncı:
Elsevier
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Özet
Infrared spectroscopy studies of trimethyl phosphate (TMP) in 17 different pure organic solvents were undertaken to investigate the solvent-solute interactions and to correlate solvent properties such as the Kirkwood-Bauer-Magat (KBM) equation, the solvent acceptor number (AN) and the linear solvation energy relationships (LSER), respectively, with the infrared band shift. Poor correlation between dielectric constants and the frequencies showed that the KBM relationship was unsuitable for the investigated molecules. These frequencies exhibited a better correlation with the LSER than the solvent AN.
Açıklama
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Konusu
Chemistry, Spectroscopy, Infrared spectroscopy, Linear solvation energy relationships, Solvent effects, Trimethyl phosphate, Solvation energy relationships, Vibrational frequency-shifts, Pi-star, IR, Systems, NMR, Hydrogen, Equation, Acetone, Solutes, Alkalinity, Hydroxylation, Molecular vibrations, Permittivity, Phosphates, Electronic polarization, Organic compounds
Alıntı
Tekin, N. ve Cebe, M. (2004). “Solvents effect on infrared spectra of trimethyl phosphate in organic solvents”. Vibrational Spectroscopy, 36(1), 129-133.