Publication:
Selective oxidative deoximation with anhydrous Ce(IV) sulfate

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dc.contributor.authorAsutay, Oktay
dc.contributor.authorHamarat, Nilüfer
dc.contributor.authorUludağ, Nesimi
dc.contributor.buuauthorCoşkun, Necdet
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.researcheridB-1200-2012
dc.contributor.scopusid7004177880
dc.date.accessioned2023-10-30T08:15:44Z
dc.date.available2023-10-30T08:15:44Z
dc.date.issued2015-06-17
dc.description.abstractAnhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes.
dc.description.sponsorshipNamık Kemal Üniversitesi (NKUBAP.00.M6.AR.12.01)
dc.identifier.citationAsutay, O. vd. (2015). "Selective oxidative deoximation with anhydrous Ce(IV) sulfate". Tetrahedron Letters, 56(25), 3902-3904.
dc.identifier.endpage3904
dc.identifier.issn0040-4039
dc.identifier.issue25
dc.identifier.scopus2-s2.0-84930181671
dc.identifier.startpage3902
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2015.04.111
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0040403915007686
dc.identifier.urihttp://hdl.handle.net/11452/34661
dc.identifier.volume56
dc.identifier.wos000356549600013
dc.indexed.wosSCIE
dc.indexed.wosCCRE
dc.language.isoen
dc.publisherElsevier
dc.relation.bapNKUBAP.00.M6.AR.12.01
dc.relation.collaborationYurt içi
dc.relation.journalTetrahedron Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemistry
dc.subjectOxidation
dc.subjectOximes
dc.subjectReaction mechanism
dc.subjectHammett correlation
dc.subjectIsonitroso hydrogen
dc.subjectParent carbonyl-compounds
dc.subjectOne-pot synthesis
dc.subjectPreparative conversion
dc.subjectEfficient
dc.subjectRegeneration
dc.subjectDerivatives
dc.subjectNitrate
dc.subject.emtree1 (dinitromethyl)benzene
dc.subject.emtreeBenzene
dc.subject.emtreeCarbonyl derivative
dc.subject.emtreeCerium
dc.subject.emtreeChlorinated hydrocarbon
dc.subject.emtreeChloroform
dc.subject.emtreeHydrogen
dc.subject.emtreeNitrile oxide
dc.subject.emtreeOxime
dc.subject.emtreeSulfate
dc.subject.emtreeUnclassified drug
dc.subject.emtreeArticle
dc.subject.emtreeChemical reaction
dc.subject.emtreeOxidative deoximation
dc.subject.emtreeRoom temperature
dc.subject.scopusOximes; Carbonyl derivative; Ketone
dc.subject.wosChemistry, organic
dc.titleSelective oxidative deoximation with anhydrous Ce(IV) sulfate
dc.typeArticle
dc.wos.quartileQ2
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

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