Yayın: Selective oxidative deoximation with anhydrous Ce(IV) sulfate
Tarih
Kurum Yazarları
Coşkun, Necdet
Yazarlar
Asutay, Oktay
Hamarat, Nilüfer
Uludağ, Nesimi
Danışman
Dil
Türü
Yayıncı:
Elsevier
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Özet
Anhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes.
Açıklama
Kaynak:
Anahtar Kelimeler:
Konusu
Chemistry, Oxidation, Oximes, Reaction mechanism, Hammett correlation, Isonitroso hydrogen, Parent carbonyl-compounds, One-pot synthesis, Preparative conversion, Efficient, Regeneration, Derivatives, Nitrate
Alıntı
Asutay, O. vd. (2015). "Selective oxidative deoximation with anhydrous Ce(IV) sulfate". Tetrahedron Letters, 56(25), 3902-3904.