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Selective oxidative deoximation with anhydrous Ce(IV) sulfate

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Coşkun, Necdet

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Asutay, Oktay
Hamarat, Nilüfer
Uludağ, Nesimi

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Elsevier

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Abstract

Anhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes.

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Keywords

Chemistry, Oxidation, Oximes, Reaction mechanism, Hammett correlation, Isonitroso hydrogen, Parent carbonyl-compounds, One-pot synthesis, Preparative conversion, Efficient, Regeneration, Derivatives, Nitrate

Citation

Asutay, O. vd. (2015). "Selective oxidative deoximation with anhydrous Ce(IV) sulfate". Tetrahedron Letters, 56(25), 3902-3904.

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