(2,2 '-bipyridine)saccharinatosilver(I)
Date
2007-12
Authors
Hamamcı, Sevim
Harrison, William T.A.
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-Blackwell
Abstract
The title complex, [Ag(C7H4NO3S)(C10H8N2)], has a mononuclear structure in which the Ag-I ion is coordinated by two N atoms from 2,2 '-bipyridine and one N atom from saccharinate, forming a distorted T-shaped (or trigonal-planar) AgN3 arrangement. The bite angle of bpy is 71.69 (6)degrees, which contributes significantly to the distortion of the coordination geometry. Molecules are connected by C-H center dot center dot center dot O and pi(bpy)-pi(bpy) interactions with a centroid-centroid separation of 3.6741 (13) angstrom.
Description
Keywords
Crystal-structure, Saccharin
Citation
Yılmaz, V. T. vd. (2007). "(2,2 '-bipyridine)saccharinatosilver(I)". Acta Crystallographica Section E: Structure Reports Online, 63, M3071-U1912.