Diethyl phthalate removal from aqueous phase using poly(EGDMA-MATrp) beads: Kinetic, isothermal and thermodynamic studies

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dc.contributor.buuauthorÖzer, Elif Tümay
dc.contributor.buuauthorOsman, Bilgen
dc.contributor.buuauthorKara, Ali
dc.contributor.buuauthorDemirbel, Emel
dc.contributor.buuauthorBeşirli, Necati
dc.contributor.buuauthorGücer, Şeref
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.contributor.orcid0000-0002-5225-0146tr_TR
dc.contributor.orcid0000-0001-8406-149Xtr_TR
dc.contributor.orcid0000-0003-2457-6314tr_TR
dc.contributor.researcheridAAI-3137-2021tr_TR
dc.contributor.researcheridABF-4791-2020tr_TR
dc.contributor.researcheridAAG-6271-2019tr_TR
dc.contributor.researcheridESF-6302-2022tr_TR
dc.contributor.researcheridCGK-8659-2022tr_TR
dc.contributor.researcheridGAV-3362-2022tr_TR
dc.contributor.scopusid37047586000tr_TR
dc.contributor.scopusid15221651200tr_TR
dc.contributor.scopusid7102824859tr_TR
dc.contributor.scopusid54681740300tr_TR
dc.contributor.scopusid6507924888tr_TR
dc.contributor.scopusid36849130600tr_TR
dc.date.accessioned2024-03-20T10:38:49Z
dc.date.available2024-03-20T10:38:49Z
dc.date.issued2015-07-03
dc.description.abstractIn this study, poly(ethylene glycol dimethacrylate-N-methacryloyl-l-tryptophan methyl ester) [poly(EGDMA-MATrp)] beads (average diameter = 106-300 mu m), which were synthesized by co-polymerizing of N-methacryloyl-l-tryptophan methyl ester (MATrp) with ethylene glycol dimethacrylate (EGDMA), were used for diethyl phthalate (DEP) adsorption. The various factors affecting the adsorption of DEP from aqueous solutions such as pH, initial concentration, contact time and temperature were analysed. Adsorption behaviour of DEP on the poly(EGDMA-MATrp) beads was investigated by varying pH values of solution, contact time, initial concentration and temperature. An optimum adsorption capacity of 590.7 mg/g for DEP was obtained at 25 degrees C. The present adsorption process obeyed a pseudo-second-order kinetic model. All the isotherm data can be fitted with the Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. Thermodynamic parameters Delta H = 7.745 kJ/mol, Delta S = 81.92 J/K/mol and Delta G = -16.69 kJ/mol to -18.31 kJ/mol with the rise in temperature from 25 degrees C to 45 degrees C indicated that the adsorption process was endothermic and spontaneous.en_US
dc.identifier.citationOzer, E. T. vd. (2015). "Diethyl phthalate removal from aqueous phase using poly(EGDMA-MATrp) beads: Kinetic, isothermal and thermodynamic studies". Environmental Technology (United Kingdom), 36(13), 1698-1706.en_US
dc.identifier.doihttps://doi.org/10.1080/09593330.2015.1006687
dc.identifier.endpage1706tr_TR
dc.identifier.issn0959-3330
dc.identifier.issn1479-487X
dc.identifier.issue13tr_TR
dc.identifier.pubmed25629452tr_TR
dc.identifier.scopus2-s2.0-84926528069
dc.identifier.startpage1698tr_TR
dc.identifier.urihttps://www.tandfonline.com/doi/full/10.1080/09593330.2015.1006687
dc.identifier.urihttps://hdl.handle.net/11452/40520
dc.identifier.volume36tr_TR
dc.identifier.wos000351845000011
dc.indexed.pubmedPubMeden_US
dc.indexed.scopusScopusen_US
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.relation.bapKUAP(F)-2012/58tr_TR
dc.relation.bapOUAP-(F)-2012/28tr_TR
dc.relation.journalEnvironmental Technology (United Kingdom)en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectEnvironmental sciences & ecologyen_US
dc.subjectAdsorptionen_US
dc.subjectDiethyl phthalateen_US
dc.subjectPolymeren_US
dc.subjectRemovalen_US
dc.subjectEndocrine-disrupting compoundsen_US
dc.subjectWaste-wateren_US
dc.subjectActivated carbonen_US
dc.subjectDimethyl phthalateen_US
dc.subjectPotential-theoryen_US
dc.subjectBasic dyeen_US
dc.subjectAdsorptionen_US
dc.subjectEstersen_US
dc.subjectAdsorbentsen_US
dc.subjectGasesen_US
dc.subjectSorptionen_US
dc.subjectDiethyl phthalateen_US
dc.subjectAliphatic compoundsen_US
dc.subjectAmino acidsen_US
dc.subjectEndocrine disruptersen_US
dc.subjectEstersen_US
dc.subjectEthyleneen_US
dc.subjectEthylene glycolen_US
dc.subjectIsothermsen_US
dc.subjectPolymersen_US
dc.subjectPolyolsen_US
dc.subjectRemovalen_US
dc.subjectTemperatureen_US
dc.subjectAdsorption capacitiesen_US
dc.subjectInitial concentrationen_US
dc.subjectEthylene glycol dimethacrylateen_US
dc.subjectPseudo-second-order kinetic modelsen_US
dc.subjectThermodynamic parameteren_US
dc.subjectThermodynamic studiesen_US
dc.subjectAqueous solutionen_US
dc.subjectEndocrine disruptoren_US
dc.subjectEsteren_US
dc.subjectIsothermen_US
dc.subjectpHen_US
dc.subjectPhthalateen_US
dc.subjectPollutant removalen_US
dc.subjectPolymeren_US
dc.subjectTemperature effecten_US
dc.subjectThermodynamicsen_US
dc.subject.emtreeActivated carbonen_US
dc.subject.emtreeAdsorbenten_US
dc.subject.emtreeAllyl compounden_US
dc.subject.emtreeEthylene glycol dimethacrylateen_US
dc.subject.emtreePhthalic acid diethyl esteren_US
dc.subject.emtreeTryptophan derivativeen_US
dc.subject.emtreeUnclassified drugen_US
dc.subject.emtree[poly(ethylene glycol dimethacrylate n methacryloyl levo trytophan methyl ester)] beaden_US
dc.subject.emtreeEthylene glycol dimethacrylateen_US
dc.subject.emtreeMethacrylic acid derivativeen_US
dc.subject.emtreeMicrosphereen_US
dc.subject.emtreeN-(2-furyl)acryloyl-L-tryptophan methyl esteren_US
dc.subject.emtreePhthalic acid derivativeen_US
dc.subject.emtreePhthalic acid diethyl esteren_US
dc.subject.emtreeTryptophanen_US
dc.subject.emtreeWater pollutanten_US
dc.subject.emtreeAdsorption kineticsen_US
dc.subject.emtreeAqueous solutionen_US
dc.subject.emtreeArticleen_US
dc.subject.emtreeBinding siteen_US
dc.subject.emtreeChemical interactionen_US
dc.subject.emtreeDesorptionen_US
dc.subject.emtreeDispersionen_US
dc.subject.emtreeEnvironmental temperatureen_US
dc.subject.emtreeIsothermen_US
dc.subject.emtreeNuclear magnetic resonance spectroscopyen_US
dc.subject.emtreepHen_US
dc.subject.emtreePolymerizationen_US
dc.subject.emtreeSynthesisen_US
dc.subject.emtreeThermodynamicsen_US
dc.subject.emtreeWaste water managementen_US
dc.subject.emtreeWater pollutionen_US
dc.subject.emtreeWater transporten_US
dc.subject.emtreeX ray photoelectron spectroscopyen_US
dc.subject.emtreeAnalogs and derivativesen_US
dc.subject.emtreeChemistryen_US
dc.subject.emtreeIsolation and purificationen_US
dc.subject.emtreeKineticsen_US
dc.subject.emtreeMaterials testingen_US
dc.subject.emtreePhase transitionen_US
dc.subject.emtreeProceduresen_US
dc.subject.emtreeTemperatureen_US
dc.subject.emtreeThermodynamicsen_US
dc.subject.emtreeThermodynamicsen_US
dc.subject.emtreeWater pollutanten_US
dc.subject.meshKineticsen_US
dc.subject.meshMaterials testingen_US
dc.subject.meshMethacrylatesen_US
dc.subject.meshMicrospheresen_US
dc.subject.meshPhase transitionen_US
dc.subject.meshPhthalic acidsen_US
dc.subject.meshTemperatureen_US
dc.subject.meshThermodynamicsen_US
dc.subject.meshTryptophanen_US
dc.subject.meshWater pollutants, chemicalen_US
dc.subject.meshWater purificationen_US
dc.subject.scopusPhthalic Acid Ester; Degradation; Mono-(2-Ethylhexyl)Phthalateen_US
dc.subject.wosEnvironmental sciencesen_US
dc.titleDiethyl phthalate removal from aqueous phase using poly(EGDMA-MATrp) beads: Kinetic, isothermal and thermodynamic studiesen_US
dc.typeArticleen_US

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