Kinetic, isotherm and thermodynamic analysis on adsorption of Cr(VI) ions from aqueous solutions by synthesis and characterization of magnetic-poly(divinylbenzene-vinylimidazole) microbeads
dc.contributor.buuauthor | Kara, Ali | |
dc.contributor.buuauthor | Demirbel, Emel | |
dc.contributor.department | Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. | tr_TR |
dc.contributor.researcherid | AAG-6271-2019 | tr_TR |
dc.contributor.scopusid | 7102824859 | tr_TR |
dc.contributor.scopusid | 54681740300 | tr_TR |
dc.date.accessioned | 2022-04-12T05:59:01Z | |
dc.date.available | 2022-04-12T05:59:01Z | |
dc.date.issued | 2012-06 | |
dc.description.abstract | The magnetic-poly(divinylbenzene-1-vinylimidazole) [m-poly(DVB-VIM)] microbeads (average diameter 53-212 mu m) were synthesized and characterized; their use as adsorbent in removal of Cr(VI) ions from aqueous solutions was investigated. The m-poly(DVB-VIM) microbeads were prepared by copolymerizing of divinylbenzene (DVB) with 1-vinylimidazole (VIM). The m-poly(DVB-VIM) microbeads were characterized by N-2 adsorption/desorption isotherms, ESR, elemental analysis, scanning electron microscope (SEM) and swelling studies. At fixed solid/solution ratio the various factors affecting adsorption of Cr(VI) ions from aqueous solutions such as pH, initial concentration, contact time and temperature were analyzed. Langmuir, Freundlich and Dubinin-Radushkvich isotherms were used as the model adsorption equilibrium data. Langmuir isotherm model was the most adequate. The pseudo-first-order, pseudo-second-order, Ritch-second-order and intraparticle diffusion models were used to describe the adsorption kinetics. The apparent activation energy was found to be 5.024 kJ mol(-1), which is characteristic of a chemically controlled reaction. The experimental data fitted to pseudo-second-order kinetic. The study of temperature effect was quantified by calculating various thermodynamic parameters such as Gibbs free energy, enthalpy and entropy changes. The thermodynamic parameters obtained indicated the endothermic nature of adsorption of Cr(VI) ions. Morever, after the use in adsorption, the m-poly(DVB-VIM) microbeads with paramagnetic property were separeted via the applied magnetic force. The magnetic beads could be desorbed up to about 97% by treating with 1.0 M NaOH. These features make the m-poly(DVB-VIM) microbeads a potential candidate for support of Cr(VI) ions removal under magnetic field. | en_US |
dc.identifier.citation | Kara, A. ve Demirbel, E. (2012). "Kinetic, isotherm and thermodynamic analysis on adsorption of Cr(VI) ions from aqueous solutions by synthesis and characterization of magnetic-poly(divinylbenzene-vinylimidazole) microbeads". Water Air & Soil Pollution, 223(5), 2387-2403. | en_US |
dc.identifier.endpage | 2403 | tr_TR |
dc.identifier.issn | 0049-6979 | |
dc.identifier.issn | 1573-2932 | |
dc.identifier.issue | 5 | tr_TR |
dc.identifier.pubmed | 22707803 | tr_TR |
dc.identifier.scopus | 2-s2.0-84862218796 | tr_TR |
dc.identifier.startpage | 2387 | tr_TR |
dc.identifier.uri | https://doi.org/10.1007/s11270-011-1032-1 | |
dc.identifier.uri | https://link.springer.com/article/10.1007/s11270-011-1032-1 | |
dc.identifier.uri | http://hdl.handle.net/11452/25715 | |
dc.identifier.volume | 223 | tr_TR |
dc.identifier.wos | 000304467000038 | tr_TR |
dc.indexed.pubmed | PubMed | en_US |
dc.indexed.scopus | Scopus | en_US |
dc.indexed.wos | SCIE | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer International Publishing | en_US |
dc.relation.bap | UAP(F)-2011/35 | tr_TR |
dc.relation.journal | Water Air & Soil Pollution | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Environmental sciences & ecology | en_US |
dc.subject | Meteorology & atmospheric sciences | en_US |
dc.subject | Water resources | en_US |
dc.subject | Magnetic polymers | en_US |
dc.subject | Adsorption isotherm | en_US |
dc.subject | Adsorption kinetic | en_US |
dc.subject | Adsorption thermodynamic | en_US |
dc.subject | Cr (VI) ions | en_US |
dc.subject | Heavy-metal ions | en_US |
dc.subject | Waste-water | en_US |
dc.subject | Activated carbon | en_US |
dc.subject | Hexavalent chromium | en_US |
dc.subject | Magnetic beads | en_US |
dc.subject | Removal | en_US |
dc.subject | Sorption | en_US |
dc.subject | Biosorption | en_US |
dc.subject | Adsorbent | en_US |
dc.subject | Chitosan | en_US |
dc.subject | Chromium compounds | en_US |
dc.subject | Desorption | en_US |
dc.subject | Dyes | en_US |
dc.subject | Ions | en_US |
dc.subject | Kinetics | en_US |
dc.subject | Magnetic fields | en_US |
dc.subject | Paramagnetism | en_US |
dc.subject | Polymethyl methacrylates | en_US |
dc.subject | Scanning electron microscopy | en_US |
dc.subject | Synthesis (chemical) | en_US |
dc.subject | Thermoanalysis | en_US |
dc.subject | Thermodynamics | en_US |
dc.subject | Adsorption equilibria | en_US |
dc.subject | Adsorption kinetics | en_US |
dc.subject | Adsorption thermodynamics | en_US |
dc.subject | Adsorption/desorption | en_US |
dc.subject | Apparent activation energy | en_US |
dc.subject | Average diameter | en_US |
dc.subject | Contact time | en_US |
dc.subject | Controlled reactions | en_US |
dc.subject | Endothermic nature | en_US |
dc.subject | Entropy changes | en_US |
dc.subject | Experimental data | en_US |
dc.subject | Freundlich | en_US |
dc.subject | Initial concentration | en_US |
dc.subject | Intraparticle diffusion models | en_US |
dc.subject | Langmuir isotherm models | en_US |
dc.subject | Langmuirs | en_US |
dc.subject | Magnetic beads | en_US |
dc.subject | Magnetic force | en_US |
dc.subject | Magnetic polymers | en_US |
dc.subject | Microbeads | en_US |
dc.subject | Paramagnetic properties | en_US |
dc.subject | Pseudo second order kinetics | en_US |
dc.subject | Solid/solution ratio | en_US |
dc.subject | Swelling studies | en_US |
dc.subject | Thermo dynamic analysis | en_US |
dc.subject | Thermodynamic parameter | en_US |
dc.subject | Adsorption | en_US |
dc.subject | Aqueous solution | en_US |
dc.subject | Benzene | en_US |
dc.subject | Chromium | en_US |
dc.subject | Isotherm | en_US |
dc.subject | Polymer | en_US |
dc.subject | Removal experiment | en_US |
dc.subject | Temperature | en_US |
dc.subject | Thermodynamics | en_US |
dc.subject | Zinc | en_US |
dc.subject.emtree | Chromium | en_US |
dc.subject.emtree | Copolymer | en_US |
dc.subject.emtree | Poly(divinylbenzene 1 vinylimidazole) | en_US |
dc.subject.emtree | Sodium hydroxide | en_US |
dc.subject.emtree | Unclassified drug | en_US |
dc.subject.emtree | Adsorption | en_US |
dc.subject.emtree | Aqueous solution | en_US |
dc.subject.emtree | Article | en_US |
dc.subject.emtree | Chemical reaction | en_US |
dc.subject.emtree | Concentration (parameters) | en_US |
dc.subject.emtree | Desorption | en_US |
dc.subject.emtree | Diffusion | en_US |
dc.subject.emtree | Electron spin resonance | en_US |
dc.subject.emtree | Enthalpy | en_US |
dc.subject.emtree | Entropy | en_US |
dc.subject.emtree | Heavy metal removal | en_US |
dc.subject.emtree | Isotherm | en_US |
dc.subject.emtree | Kinetics | en_US |
dc.subject.emtree | Magnetic field | en_US |
dc.subject.emtree | Magnetism | en_US |
dc.subject.emtree | Ph | en_US |
dc.subject.emtree | Polymerization | en_US |
dc.subject.emtree | Scanning electron microscopy | en_US |
dc.subject.emtree | Synthesis | en_US |
dc.subject.emtree | Temperature | en_US |
dc.subject.emtree | Thermodynamics | en_US |
dc.subject.scopus | Chromium Hexavalent Ion; Biosorbents; Second-Order Model | en_US |
dc.subject.wos | Environmental sciences | en_US |
dc.subject.wos | Meteorology & atmospheric sciences | en_US |
dc.subject.wos | Water resources | en_US |
dc.title | Kinetic, isotherm and thermodynamic analysis on adsorption of Cr(VI) ions from aqueous solutions by synthesis and characterization of magnetic-poly(divinylbenzene-vinylimidazole) microbeads | en_US |
dc.type | Article | |
dc.wos.quartile | Q2 | en_US |