Effects of sampling interval on the passive air sampling of atmospheric PCBs levels

Abstract

In this study, we collected Polychlorinated biphenyls (PCBs) using passive air samplers (PASs), between February 4, 2013 and February 2, 2014, with the sampling periods ranging from 10 to 60days. The samples were collected with PASs that contained polyurethane foam (PUF). With these samples, 87 PCB congeners were analyzed. Sampling coefficient (R) values for the four seasons were calculated using both the high volume air sampler (HVAS) and PAS samples collected with the same time interval. The average of the annual concentrations of 87 PCB congeners, calculated using the R values specific to this study, was 234 +/- 175pg/m(3). PCB congeners with 3- and 4- chlorines were dominant. The samples were collected at the same time interval but at different times to represent accumulation in the PASs. The linear regression coefficients (r) of the PCB mass accumulated in PASs against time ranged from 0.89 and 0.97 indicating that accumulation was linear. Moreover, the concentrations of the PCB congeners were statistically correlated with atmospheric conditions.