Publication: Synthesis, characterization and crystal structures of platinum(II) saccharinate complexes with 1,5-cyclooctadiene
dc.contributor.author | İcsel, Ceyda | |
dc.contributor.buuauthor | İÇSEL YILMAZ, CEYDA | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Kimya Bölümü | |
dc.contributor.orcid | 0000-0002-2717-2430 | |
dc.contributor.researcherid | AAI-3342-2021 | |
dc.date.accessioned | 2024-07-05T11:55:37Z | |
dc.date.available | 2024-07-05T11:55:37Z | |
dc.date.issued | 2020-04-24 | |
dc.description.abstract | Two new platinum(II) complexes, namely [PtCl(sac)(COD)] (1) and [Pt(sac)(2) (COD)] (2) (sac = saccharinate and COD = 1,5-cyclooctadiene), were synthesized and characterized by elemental analysis, IR, NMR, ESI-MS spectroscopic and thermal analysis (TG/DTA) methods. The platinum(II) complexes were prepared from the reaction of [PtCl2 (COD)] with Na(sac)center dot 2H(2)O. The addition of the sac ligand resulted in the replacement of 1 and 2 chlorido ligands in [PtCl2 (COD)] to yield 1 and 2, respectively. The structures of the complexes were determined by single crystal X-ray diffraction and showed a distorted square planar coordination geometry around platinum(II). COD acted as a p-donor ligand, while sac was N-coordinated in both complexes. The TG/DTA data indicated that both complexes were thermally stable up to 220 degrees C in air and their thermal decompositions yielded Pt as a final product. Complexes 1 and 2 were also designed as possible precursors to synthesize new mixed-ligand platinum(II) sac complexes in a one-pot reaction. | |
dc.identifier.doi | 10.3906/kim-2002-34 | |
dc.identifier.endpage | 745 | |
dc.identifier.issn | 1300-0527 | |
dc.identifier.issue | 3 | |
dc.identifier.startpage | 736 | |
dc.identifier.uri | https://doi.org/10.3906/kim-2002-34 | |
dc.identifier.uri | https://journals.tubitak.gov.tr/chem/vol44/iss3/15/ | |
dc.identifier.uri | https://hdl.handle.net/11452/42985 | |
dc.identifier.volume | 44 | |
dc.identifier.wos | 000538115400015 | |
dc.indexed.wos | WOS.SCI | |
dc.language.iso | en | |
dc.publisher | TÜBİTAK | |
dc.relation.journal | Turkish Journal of Chemistry | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.subject | Antiproliferative activity | |
dc.subject | Organometallic palladium | |
dc.subject | Organoplatinum(ii) | |
dc.subject | Cytotoxicity | |
dc.subject | Pt(II) complex | |
dc.subject | Saccharinate | |
dc.subject | 1,5-cyclooctadiene | |
dc.subject | Crystal structure | |
dc.subject | Chemistry | |
dc.subject | Engineering | |
dc.title | Synthesis, characterization and crystal structures of platinum(II) saccharinate complexes with 1,5-cyclooctadiene | |
dc.type | Article | |
dspace.entity.type | Publication | |
local.contributor.department | Fen Edebiyat Fakültesi/Kimya Bölümü | |
relation.isAuthorOfPublication | 0097eb1b-8a3c-4f68-b25f-e9be30926fa3 | |
relation.isAuthorOfPublication.latestForDiscovery | 0097eb1b-8a3c-4f68-b25f-e9be30926fa3 |
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