Publication:
Coordination versatility of 2,2 '-(ethylenedioxy)bis(ethylamine) in new mono- and polynuclear metal(II) complexes of saccharinate: Synthesis, characterization and crystal structures

dc.contributor.authorKaradaǧ, Ahmet
dc.contributor.authorGözüaçık, Ayşe Keskin
dc.contributor.authorYerli, Yusuf
dc.contributor.authorŞahin, Ertan
dc.contributor.buuauthorYılmaz, Veysel Turan
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-2849-3332
dc.contributor.researcheridL-7238-2018
dc.contributor.scopusid7006269202
dc.date.accessioned2024-03-01T12:14:19Z
dc.date.available2024-03-01T12:14:19Z
dc.date.issued2014-03-23
dc.description.abstractThe reaction of [M(sac)(2)(H2O)(4)]center dot 2H2(O) (M = Ni-II Cu-II, Cd(II)a nd sac = saccharinate) with 2,2'(ethylenedioxy)bis(ethylarnine) (edbea) resulted in [Ni(edbea)(sac)(2)]center dot 2H(2)O (1) [Cu(edbea)(sac)(2)] (2), [Cu(g-edbea)(sac)(2)](n) (3) and [Cd(edbea)2](sac)2 (4), which have been characterized by elemental analyses, magnetic measurements, FT-IR and EPR (for 3) spectroscopies, thermal analysis, magnetic properties (for 1 and 3) and X-ray diffraction methods. The edbea ligand display different coordination modes in the present complexes. For example, 1 and 2 it acts a tridentate way, while it exhibits a mu-N/O bidentate bridging mode between the copper centers in 3. On the other hand, the geometry of 4 eight-coordinated by two tetradentate edbea ligands is the bicapped trigonal prism structure in which S(degrees) value is the smallest. The EPR spectrum of 3 showed that the local geometry of Cu(II) ion has an elongated rhombic coordination. Complexes 1 and 3 exhibited a paramagnetic behavior as expected, but complex 1 displayed an antiferromagnetic interaction at low temperatures.
dc.identifier.citationKaradağ, A. vd. (2014). "Coordination versatility of 2,2 '-(ethylenedioxy)bis(ethylamine) in new mono- and polynuclear metal(II) complexes of saccharinate: Synthesis, characterization and crystal structures". Polyhedron, 78, 24-30.
dc.identifier.doihttps://doi.org/10.1016/j.poly.2014.03.056
dc.identifier.endpage30
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84899903716
dc.identifier.startpage24
dc.identifier.urihttps://pdf.sciencedirectassets.com/271375/1-s2.0-S0277538714X00094/1-s2.0-S027753871400206X/main.pdf
dc.identifier.urihttps://hdl.handle.net/11452/40152
dc.identifier.volume78
dc.identifier.wos000337883800004
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherElsevier
dc.relation.collaborationYurt içi
dc.relation.journalPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject2,2′-(Ethylenedioxy)bis(ethylamine)
dc.subjectThermal analysis
dc.subjectCrystal structures
dc.subjectMagnetic properties
dc.subjectSaccharin
dc.subjectDeprotonated saccharin
dc.subjectCopper(ii) complexes
dc.subjectCrystallization
dc.subjectCu2+
dc.subjectChemistry
dc.subjectCrystallography
dc.subject2
dc.subjectBridging mode
dc.subjectComplex 1
dc.subjectCoordination modes
dc.subjectCopper centers
dc.subjectCrystals structures
dc.subjectEthylamine
dc.subjectSaccharinate
dc.subjectX-ray diffraction method
dc.subject.scopusComplex; Palladium; 2-Phenylpyridine
dc.subject.wosChemistry, inorganic & nuclear
dc.subject.wosCrystallography
dc.titleCoordination versatility of 2,2 '-(ethylenedioxy)bis(ethylamine) in new mono- and polynuclear metal(II) complexes of saccharinate: Synthesis, characterization and crystal structures
dc.typeArticle
dc.wos.quartileQ2
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atWOS
local.indexed.atScopus

Files

License bundle

Now showing 1 - 1 of 1
Placeholder
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description: