Publication: Coordination versatility of 2,2 '-(ethylenedioxy)bis(ethylamine) in new mono- and polynuclear metal(II) complexes of saccharinate: Synthesis, characterization and crystal structures
dc.contributor.author | Karadaǧ, Ahmet | |
dc.contributor.author | Gözüaçık, Ayşe Keskin | |
dc.contributor.author | Yerli, Yusuf | |
dc.contributor.author | Şahin, Ertan | |
dc.contributor.buuauthor | Yılmaz, Veysel Turan | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Kimya Bölümü | |
dc.contributor.orcid | 0000-0002-2849-3332 | |
dc.contributor.researcherid | L-7238-2018 | |
dc.contributor.scopusid | 7006269202 | |
dc.date.accessioned | 2024-03-01T12:14:19Z | |
dc.date.available | 2024-03-01T12:14:19Z | |
dc.date.issued | 2014-03-23 | |
dc.description.abstract | The reaction of [M(sac)(2)(H2O)(4)]center dot 2H2(O) (M = Ni-II Cu-II, Cd(II)a nd sac = saccharinate) with 2,2'(ethylenedioxy)bis(ethylarnine) (edbea) resulted in [Ni(edbea)(sac)(2)]center dot 2H(2)O (1) [Cu(edbea)(sac)(2)] (2), [Cu(g-edbea)(sac)(2)](n) (3) and [Cd(edbea)2](sac)2 (4), which have been characterized by elemental analyses, magnetic measurements, FT-IR and EPR (for 3) spectroscopies, thermal analysis, magnetic properties (for 1 and 3) and X-ray diffraction methods. The edbea ligand display different coordination modes in the present complexes. For example, 1 and 2 it acts a tridentate way, while it exhibits a mu-N/O bidentate bridging mode between the copper centers in 3. On the other hand, the geometry of 4 eight-coordinated by two tetradentate edbea ligands is the bicapped trigonal prism structure in which S(degrees) value is the smallest. The EPR spectrum of 3 showed that the local geometry of Cu(II) ion has an elongated rhombic coordination. Complexes 1 and 3 exhibited a paramagnetic behavior as expected, but complex 1 displayed an antiferromagnetic interaction at low temperatures. | |
dc.identifier.citation | Karadağ, A. vd. (2014). "Coordination versatility of 2,2 '-(ethylenedioxy)bis(ethylamine) in new mono- and polynuclear metal(II) complexes of saccharinate: Synthesis, characterization and crystal structures". Polyhedron, 78, 24-30. | |
dc.identifier.doi | https://doi.org/10.1016/j.poly.2014.03.056 | |
dc.identifier.endpage | 30 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.scopus | 2-s2.0-84899903716 | |
dc.identifier.startpage | 24 | |
dc.identifier.uri | https://pdf.sciencedirectassets.com/271375/1-s2.0-S0277538714X00094/1-s2.0-S027753871400206X/main.pdf | |
dc.identifier.uri | https://hdl.handle.net/11452/40152 | |
dc.identifier.volume | 78 | |
dc.identifier.wos | 000337883800004 | |
dc.indexed.wos | SCIE | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.relation.collaboration | Yurt içi | |
dc.relation.journal | Polyhedron | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | 2,2′-(Ethylenedioxy)bis(ethylamine) | |
dc.subject | Thermal analysis | |
dc.subject | Crystal structures | |
dc.subject | Magnetic properties | |
dc.subject | Saccharin | |
dc.subject | Deprotonated saccharin | |
dc.subject | Copper(ii) complexes | |
dc.subject | Crystallization | |
dc.subject | Cu2+ | |
dc.subject | Chemistry | |
dc.subject | Crystallography | |
dc.subject | 2 | |
dc.subject | Bridging mode | |
dc.subject | Complex 1 | |
dc.subject | Coordination modes | |
dc.subject | Copper centers | |
dc.subject | Crystals structures | |
dc.subject | Ethylamine | |
dc.subject | Saccharinate | |
dc.subject | X-ray diffraction method | |
dc.subject.scopus | Complex; Palladium; 2-Phenylpyridine | |
dc.subject.wos | Chemistry, inorganic & nuclear | |
dc.subject.wos | Crystallography | |
dc.title | Coordination versatility of 2,2 '-(ethylenedioxy)bis(ethylamine) in new mono- and polynuclear metal(II) complexes of saccharinate: Synthesis, characterization and crystal structures | |
dc.type | Article | |
dc.wos.quartile | Q2 | |
dspace.entity.type | Publication | |
local.contributor.department | Fen Edebiyat Fakültesi/Kimya Bölümü | |
local.indexed.at | WOS | |
local.indexed.at | Scopus |
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