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Synthesis of corrosion preventive long-chain N-alkyl-2-(phenylthio)-acetohydrazides and 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates

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dc.contributor.buuauthorYıldırım, Ayhan
dc.contributor.buuauthorÇetin, Mehmet
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-2328-9754
dc.contributor.researcheridW-8924-2019
dc.contributor.scopusid23101773900
dc.contributor.scopusid7101936230
dc.date.accessioned2024-03-19T10:01:18Z
dc.date.available2024-03-19T10:01:18Z
dc.date.issued2008-11
dc.description.abstractLong-chain N-alkyl-2-(phenylthio)acetohydrazides were synthesized via the reactions of 2-(phenylthio)acetohydrazide with long-straight-chain aldehydes and then reduction with sodium borohydride. The reactions of long-straight-chain hydrazides with carbon disulfide in alkaline media give the corresponding carbodithioate salts. Heating of potassium 2-alkanoylhydrazinecarbodithioates with phenacyl bromide do not yield cyclization and failed to give the corresponding long-chain thiazolidine-2-thiones, but gave the corresponding 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates via nucleophilic substitution reaction. In addition, the synthesized compounds were tested for their corrosion prevention capabilities in acidic or in mineral oil media.
dc.identifier.citationYıldırım, A. ve Çetin, M. (2008). "Synthesis of corrosion preventive long-chain N-alkyl-2-(phenylthio)-acetohydrazides and 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates". Monatshefte fur Chemie, 139(11), 1279-1283.
dc.identifier.doi10.1007/s00706-008-0933-1
dc.identifier.endpage1283
dc.identifier.issn0026-9247
dc.identifier.issue11
dc.identifier.scopus2-s2.0-55349140411
dc.identifier.startpage1279
dc.identifier.urihttps://link.springer.com/article/10.1007/s00706-008-0933-1
dc.identifier.urihttps://hdl.handle.net/11452/40486
dc.identifier.volume139
dc.identifier.wos000260618700001
dc.indexed.wosSCIE
dc.indexed.wosIC
dc.language.isoen
dc.publisherSpringer Wien
dc.relation.bap2004/44
dc.relation.journalMonatshefte fur Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAcidic
dc.subjectCorrosion inhibitors
dc.subjectFatty acids
dc.subjectMineral oil media
dc.subjectSurface
dc.subjectChemistry
dc.subjectWell steel n-80
dc.subjectMild-steel
dc.subjectDerivatives
dc.subjectAcid
dc.subjectInhibitors
dc.subject.scopusThiazole Derivative; Antineoplastic Activity; Pyrazoles
dc.subject.wosChemistry, multidisciplinary
dc.titleSynthesis of corrosion preventive long-chain N-alkyl-2-(phenylthio)-acetohydrazides and 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates
dc.typeArticle
dc.wos.quartileQ2 (Chemistry, multidisciplinary)
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atWOS
local.indexed.atScopus

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