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Syntheses of two diamine substituted 1,3-distal calix[4]arene-based magnetite nanoparticles for extraction of dichromate, arsenate and uranyl ions

dc.contributor.authorSayın, Serkan
dc.contributor.authorYılmaz, Mustafa
dc.contributor.buuauthorTavaşlı, Mustafa
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Ana Bilim Dalı
dc.contributor.orcid0000-0002-9466-1111
dc.contributor.researcheridAAB-1630-2020
dc.contributor.scopusid6506308760
dc.date.accessioned2021-11-30T06:58:03Z
dc.date.available2021-11-30T06:58:03Z
dc.date.issued2011-05-20
dc.description.abstractThe synthesis of two new calixarene derivatives 4 and 5, functionalized at the lower rim with 4-amino-1-benzylpiperidine to give diamide and diamine derivatives of p-tert-butylcalix[4]arene, is described. They were obtained by the reaction of both the diester derivative of p-tert-butylcalix[4]arene (2) and the dialkyl bromide derivative of p-tert-butylcalix[4]arene (3) with 4-amino-1-benzylpiperidine. The (1)H NMR spectra of calixarene derivatives show that 4 and 5 exist in the cone conformation. Moreover, these diamide and diamine derivatives of p-tert-butylcalix[4]arene (4 and 5) have been immobilized onto 13-(2,3-epoxypropoxy)-Propyl]-trimethoxysilane-modified Fe(3)O(4) magnetite nanoparticles to obtain calixarene-based magnetic nanoparticles M-DADBP-Calix (6) and M-DABP-Calix (7). The calix[4]arene immobilized materials were characterized by a combination of Fourier Transform Infrared Spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and Thermogravimetric Analyses (TGA) and elemental analysis. Additionally, the studies regarding the removal of As(V)/Cr(VI) ions as well as U(VI) ion from aqueous solutions were also carried out by using these compounds in liquid liquid/solid liquid extraction experiments. (C) 2011 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipSelçuk Üniversitesi
dc.identifier.citationSayin, S. vd. (2011). "Syntheses of two diamine substituted 1,3-distal calix[4]arene-based magnetite nanoparticles for extraction of dichromate, arsenate and uranyl ions". Tetrahedron, 67(20), 3743-3753.
dc.identifier.endpage3753
dc.identifier.issn0040-4020
dc.identifier.issue20
dc.identifier.scopus2-s2.0-79955521289
dc.identifier.startpage3743
dc.identifier.urihttps://doi.org/10.1016/j.tet.2011.03.012
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0040402011003371
dc.identifier.urihttp://hdl.handle.net/11452/22868
dc.identifier.volume67
dc.identifier.wos000290889600019
dc.indexed.scopusScopus
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherPergamon-Elsevier Science
dc.relation.collaborationYurt içi
dc.relation.journalTetrahedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.relation.tubitak107T873
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemistry
dc.subjectCalix[4]arene
dc.subjectMagnetite nanoparticles
dc.subjectExtraction
dc.subjectArsenate/dichromate
dc.subjectUranyl
dc.subjectSpectrophotometric determination
dc.subjectBiomedical applications
dc.subjectSelective extraction
dc.subjectChromium(vi)
dc.subjectComplexation
dc.subjectAdsorption
dc.subjectChemistry
dc.subjectAnions
dc.subjectConformation
dc.subjectCalixarenes
dc.subject.emtree1,3 distal calix[4]arene
dc.subject.emtree3 (2,3epoxypropoxy) propyl] trimethoxysilane
dc.subject.emtree4 amino 1 benzylpiperidine
dc.subject.emtreeArsenic acid
dc.subject.emtreeBlack iron oxide magnetite
dc.subject.emtreeBromine derivative
dc.subject.emtreeChemical compound
dc.subject.emtreeDiamide
dc.subject.emtreeDiamidine derivative
dc.subject.emtreeDiamine
dc.subject.emtreeDichromic acid
dc.subject.emtreeMagnetite
dc.subject.emtreeNanoparticle
dc.subject.emtreePara tert butylcalix[4]arene
dc.subject.emtreeUnclassified drug
dc.subject.emtreeUranyl derivative
dc.subject.emtreeArticle
dc.subject.emtreeChemical structure
dc.subject.emtreeElemental analysis
dc.subject.emtreeInfrared spectroscopy
dc.subject.emtreePriority journal
dc.subject.emtreeSynthesis
dc.subject.emtreeThermogravimetry
dc.subject.emtreeTransmission electron microscopy
dc.subject.scopusCalix(4)Arene; Aromatic Hydrocarbons; Picrates
dc.subject.wosChemistry, organic
dc.titleSyntheses of two diamine substituted 1,3-distal calix[4]arene-based magnetite nanoparticles for extraction of dichromate, arsenate and uranyl ions
dc.typeArticle
dc.wos.quartileQ2
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Ana Bilim Dalı
local.indexed.atWOS
local.indexed.atScopus

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