Publication: Adsorptive removal of 4-hydroxybenzoic acid via cross-linked polymeric microbeads: Analysis of isothermal, kinetic and thermodynamic parameters
dc.contributor.author | Özer, Elif Tumay | |
dc.contributor.author | Osman, Bilgen | |
dc.contributor.buuauthor | KÜÇÜK, MELİKE | |
dc.contributor.buuauthor | OSMAN, BİLGEN | |
dc.contributor.buuauthor | TÜMAY ÖZER, ELİF | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Kimya Bölümü | |
dc.contributor.orcid | 0000-0001-8406-149X | |
dc.contributor.researcherid | JCP-4547-2023 | |
dc.date.accessioned | 2024-09-23T08:19:02Z | |
dc.date.available | 2024-09-23T08:19:02Z | |
dc.date.issued | 2023-05-26 | |
dc.description.abstract | In this study, the performance of cross-linked microbeads prepared through suspension polymerization was investigated for removal of 4-hydroxybenzoic acid (4-HBA) from aqueous solution. Adsorption studies were conducted at different pHs (2.0-8.0), temperatures (282-308 K) and initial 4-HBA concentrations (1-500 mg/L). The maximum 4-HBA adsorption was 49.05 +/- 2.89 mg/g at pH 2.0 (282 K). The adsorption data obeyed to the Langmuir isotherm model. The modified Ritchie second-order and the pseudo second-order kinetic model fitted the adsorption data. The 4-HBA adsorption capacity did not significantly change after 10 consecutive usages. Gibbs free energy changes of the adsorption were calculated as -24.372, -28.431 and -29.093 kJ/mol for 282, 298 and 308 K, respectively. The microbeads were also used for the removal of 4-HBA from spiked river water samples. The removal efficiencies of 43.2% to 68.8% and RSDs of 0.49% to 4.78% demonstrated the usability of the microbeads in application. | |
dc.identifier.doi | 10.1080/00986445.2023.2218271 | |
dc.identifier.endpage | 55 | |
dc.identifier.issn | 0098-6445 | |
dc.identifier.issue | 1 | |
dc.identifier.startpage | 40 | |
dc.identifier.uri | https://doi.org/10.1080/00986445.2023.2218271 | |
dc.identifier.uri | https://hdl.handle.net/11452/45029 | |
dc.identifier.volume | 211 | |
dc.identifier.wos | 000999550000001 | |
dc.indexed.wos | WOS.SCI | |
dc.language.iso | en | |
dc.publisher | Taylor & Francis Inc | |
dc.relation.journal | Chemical Engineering Communications | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | Solid-phase extraction | |
dc.subject | Aqueous-solution | |
dc.subject | Phenolic-compounds | |
dc.subject | Benzoic-acid | |
dc.subject | Competitive adsorption | |
dc.subject | Hydroxybenzoic acids | |
dc.subject | Activated carbon | |
dc.subject | Sorption | |
dc.subject | Phthalate | |
dc.subject | Wastewaters | |
dc.subject | 4-hydroxybenzoic acid | |
dc.subject | Adsorption | |
dc.subject | Isotherm | |
dc.subject | Kinetic | |
dc.subject | Polymeric microbeads | |
dc.subject | Removal | |
dc.subject | Thermodynamic | |
dc.subject | Science & technology | |
dc.subject | Technology | |
dc.subject | Engineering, chemical | |
dc.subject | Engineering | |
dc.title | Adsorptive removal of 4-hydroxybenzoic acid via cross-linked polymeric microbeads: Analysis of isothermal, kinetic and thermodynamic parameters | |
dc.type | Article | |
dspace.entity.type | Publication | |
local.contributor.department | Fen Edebiyat Fakültesi/Kimya Bölümü | |
relation.isAuthorOfPublication | a8929334-e152-4381-b858-568df8592e0d | |
relation.isAuthorOfPublication | b696c48b-ee92-4822-be1f-c84f4fe0e3a6 | |
relation.isAuthorOfPublication | 7b3ec35a-e96e-4664-8c05-e423a7662a1a | |
relation.isAuthorOfPublication.latestForDiscovery | a8929334-e152-4381-b858-568df8592e0d |