High-performance pszt-psmi-pszs ceramics: Piezoelectric and ferroelectric insights for advanced applications

Abstract

High-performance ferroelectric materials have garnered increased attention due to their exceptional dielectric, piezoelectric, and electrostrictive properties. A solid-state reaction method was used to prepare the perovskite Pb(1-x)Smx[(Zr0.52Ti0.48)(0.9)(Mo1/3In2/3)(0.05)(Zn1/3Sb2/3)(0.05)]O-3 (where x = 0, 0.02, 0.04, 0.06, and 0.08) ceramics, abbreviated PSZT-PSMI-PSZS. Energy-dispersive X-ray spectroscopy (EDX) and Fourier-transform infrared (FTIR) spectroscopy were employed to verify the elemental composition and molecular structure, respectively. The results showed good agreement between nominal and measured compositions, and indicated structural changes post-calcination, suggesting successful formation of the perovskite phase. Piezoelectric properties were evaluated, revealing the highest piezoelectric coefficient (d(33) = 310 pC/N) at x = 0.02, attributed to optimal morphological features and the morphotropic phase boundary effect. This sample also demonstrated the highest electromechanical coupling factors (k(p) = 60 %, k(31) = 35 %) and the largest impedance resonance frequency difference (Delta f = 15.05 kHz). Ferroelectric testing indicated excellent ferroelectric characteristics, with the maximum remanent polarization (P-r = 17.71 mu C/cm(2)) and saturation polarization (P-s = 22.75 mu C/cm(2)) observed at x = 0.02, along with the lowest coercive field (E-c=10.16 kV/cm). Additionally, this composition exhibited the highest unipolar strain (S-max = 0.17 %) and the inverse piezoelectric coefficient (d*(33) = 427.57 p.m./V). This comprehensive analysis emphasizes the potential of Sm-doped PZT-PMI-PZS ceramics for advanced piezoelectric and ferroelectric applications, particularly at a doping concentration of x = 0.02, where the materials exhibited excellent electrical and mechanical properties.