Publication: Supercritical carbon dioxide application using hydantoin acrylamide for biocidal functionalization of polyester
dc.contributor.author | Orhan, Mehmet | |
dc.contributor.author | Demirci, Fatma | |
dc.contributor.author | Koçer, Hasan B. | |
dc.contributor.author | Nierstrasz, Vincent | |
dc.contributor.buuauthor | ORHAN, MEHMET | |
dc.contributor.department | Bursa Uludağ Üniversitesi/Tekstil Mühendisliği Bölümü/Mühendislik Fakültesi | |
dc.contributor.orcid | 0000-0001-8043-4148 | |
dc.contributor.researcherid | AAG-8034-2021 | |
dc.date.accessioned | 2024-07-04T10:54:43Z | |
dc.date.available | 2024-07-04T10:54:43Z | |
dc.date.issued | 2020-11-01 | |
dc.description.abstract | Biocidal functionalization in polyester fibers is a really tough challenge because of the lack of tethering groups. This study indicated supercritical carbon dioxide application using N-halamine would be an alternative solution for obtaining antibacterial function on the polyester surface. Firstly, N-(2-methyl 1-(4 methyl-2,5-dioxo-imidazolidin-4 yl)propan-2-yl)acrylamide was synthesized and applied to the polyester in supercritical carbon dioxide medium, at 120 degrees C, 30 MPa for different processing times. The addition of N-halamine on the surface significantly brought antibacterial activity against E. coli. The chlorine loadings showed that 6-h exposure time was critical to obtain sufficient antibacterial activity. This treatment caused a reasonable and tolerable loss in color and mechanical properties. But, the durability to abrasion, stability, and rechargeability of oxidative chlorine, and the durability of N-halamine on the surface were remarkably good. Conclusively, it can be available to work on polyester surfaces with resource-efficient and eco-friendly supercritical carbon dioxide technique for getting more functionalization and modification. (C) 2020 Elsevier B.V. All rights reserved. | |
dc.identifier.doi | 10.1016/j.supflu.2020.104986 | |
dc.identifier.eissn | 1872-8162 | |
dc.identifier.issn | 0896-8446 | |
dc.identifier.uri | https://doi.org/10.1016/j.supflu.2020.104986 | |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0896844620302370?via%3Dihub | |
dc.identifier.uri | https://hdl.handle.net/11452/42900 | |
dc.identifier.volume | 165 | |
dc.identifier.wos | 000558740300026 | |
dc.indexed.wos | WOS.SCI | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.relation.journal | Journal of Supercritical Fluids | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | |
dc.relation.tubitak | BIDEB 2219 | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | N-halamine | |
dc.subject | Antibacterial activity | |
dc.subject | Nonwoven fabrics | |
dc.subject | Cotton fabrics | |
dc.subject | Triclosan | |
dc.subject | Polymers | |
dc.subject | Copolymers | |
dc.subject | Agent | |
dc.subject | Acid | |
dc.subject | Polysiloxane | |
dc.subject | Supercritical carbon dioxide (scco(2)) | |
dc.subject | N-halamine | |
dc.subject | Polyester | |
dc.subject | Antibacterial surface modification | |
dc.subject | Science & technology | |
dc.subject | Physical sciences | |
dc.subject | Technology | |
dc.subject | Chemistry, physical | |
dc.subject | Engineering, chemical | |
dc.subject | Chemistry | |
dc.subject | Engineering | |
dc.title | Supercritical carbon dioxide application using hydantoin acrylamide for biocidal functionalization of polyester | |
dc.type | Article | |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 4ead4e45-18cc-4ad7-bf85-58500677471e | |
relation.isAuthorOfPublication.latestForDiscovery | 4ead4e45-18cc-4ad7-bf85-58500677471e |