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A three-dimensional silver(I) coordination polymer involving a new bridging mode of saccharinate

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dc.contributor.authorBüyükgüngör, Orhan
dc.contributor.buuauthorGüney, Emel
dc.contributor.buuauthorYılmaz, Veysel Turan
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-2849-3332
dc.contributor.researcheridL-7238-2018
dc.contributor.scopusid25027291500
dc.contributor.scopusid7006269202
dc.date.accessioned2021-12-09T08:02:01Z
dc.date.available2021-12-09T08:02:01Z
dc.date.issued2010-04
dc.description.abstractA three-dimensional silver(I)-saccharinato (sac) coordination polymer [Ag-2(mu-Sac)21,, has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by the imino N and carbonyl O atoms of two sac ligands, leading to a dimer [Ag-2(mu-sac)(2)] with a very short Ag-Ag contact of 2.8622(6) angstrom. The dimeric units are linked by unique Ag-C-sac (eta(1)) bonds into two-dimensional ladder-like layers, which are further assembled into a three-dimensional network by weak Ag ...O(sulphonyl) and pi(sac) ... pi(sac) interactions. Complex 1 is the first example of a polymeric network involving the eta(1) Ag-C bonds. In addition to the new coordination mode of sac, the IR spectrum and thermal properties of the complex were discussed.
dc.identifier.citationGüney, E. vd. (2010). "A three-dimensional silver(I) coordination polymer involving a new bridging mode of saccharinate". Inorganic Chemistry Communications, 13(4), 563-567.
dc.identifier.doi10.1016/j.inoche.2010.02.005
dc.identifier.endpage567
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.issue4
dc.identifier.scopus2-s2.0-77949541612
dc.identifier.startpage563
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2010.02.005
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S138770031000064X
dc.identifier.urihttp://hdl.handle.net/11452/23118
dc.identifier.volume13
dc.identifier.wos000276751000029
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherElsevier
dc.relation.collaborationYurt içi
dc.relation.journalInorganic Chemistry Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectSaccharinate
dc.subjectSilver(I)
dc.subjectCoordination polymer
dc.subjectAg-C bond
dc.subjectAg ... Ag interaction
dc.subjectCrystal-structures
dc.subjectIR-spectra
dc.subjectThermal-analysis
dc.subjectComplexes
dc.subjectPyrazine
dc.subjectFtır
dc.subjectChemistry
dc.subject.scopusBenzisothiazole; Palladium; 2-Phenylpyridine
dc.subject.wosChemistry, inorganic & nuclear
dc.titleA three-dimensional silver(I) coordination polymer involving a new bridging mode of saccharinate
dc.typeArticle
dc.wos.quartileQ2
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

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