Publication:
Synthesis, structures and catalytic activity of Pd(II) saccharinate complexes with monophosphines in direct arylation of five-membered heteroarenes with aryl bromides

Simple item page
dc.contributor.authorAygün, Muhittin
dc.contributor.authorEvren, Enes
dc.contributor.authorÖzdemir, İsmail
dc.contributor.buuauthorYılmaz, Veysel T.
dc.contributor.buuauthorİçsel, Ceyda
dc.contributor.buuauthorTurgut, Ömer R.
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-2849-3332
dc.contributor.orcid0000-0002-2717-2430
dc.contributor.researcheridDZR-9362-2022
dc.contributor.scopusid56441123900
dc.contributor.scopusid55551960400
dc.contributor.scopusid57202496927
dc.date.accessioned2023-01-16T13:39:00Z
dc.date.available2023-01-16T13:39:00Z
dc.date.issued2020-01-24
dc.description.abstractA number of new Pd(II) saccharinate (sac) complexes bearing a range of phenyl (Ph), cyclohexyl (Cy) and alkyl (Me and Et) substituted tertiary phosphine ligands with systematically changing electronic and steric properties, namely trans-[PdCl(sac)(L)(2)] (L = PPh3 (1); PPh2Cy (3)), trans-[Pd(sac)(2)(H2O)(L)] (L = PPh3 (2); PPh2Cy (5)), trans-[Pd(sac)(2)(L)(2)] (L = PPh2Cy (4); PPhCy2 (6); PCy3 (8)), [PdCl(sac)(PCy3)(DMSO)] (7), trans-[Pd (sac)(2)(PPh2Me)(DMSO)] (9) and cis-[M(sac)(2)(L)(2)] (L= PPhMe2 (10); PPh2Et (11); PPhEt2 (12)), were synthesized and structurally characterized. The Pd(II) complexes were applied for direct C2/C5 arylation of fivemembered heteroarenes such as furan, thiophene and thiazole derivatives with aryl bromides. Notably, arylation products up to 99% yields were obtained in the presence of the Pd(II) complexes. The catalytic mechanism of the direct arylation was proposed to proceed via a Pd(0)/Pd(II) pathway, due to elimination of the sac ligand in the Pd(II) complexes during catalysis.
dc.identifier.citationYılmaz, V. T. vd. (2020). "Synthesis, structures and catalytic activity of Pd(II) saccharinate complexes with monophosphines in direct arylation of five-membered heteroarenes with aryl bromides". Inorganica Chimica Acta, 500.
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85074252648
dc.identifier.urihttps://doi.org/10.1016/j.ica.2019.119220
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0020169319310837
dc.identifier.urihttp://hdl.handle.net/11452/30482
dc.identifier.volume500
dc.identifier.wos000505940600008
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherElsevier Science
dc.relation.collaborationYurt içi
dc.relation.journalInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.relation.tubitak215Z230
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemistry
dc.subjectPalladium(II)
dc.subjectSaccharinate
dc.subjectPhosphine
dc.subjectCatalysis
dc.subjectArylation
dc.subjectHeteroarenes
dc.subjectPD-imidate complexes
dc.subjectPalladium complexes
dc.subjectEfficient catalysts
dc.subjectCoupling reactions
dc.subjectLigands
dc.subjectFunctionalization
dc.subjectNucleosides
dc.subjectMechanism
dc.subjectCarbene
dc.subjectHalides
dc.subjectAromatic compounds
dc.subjectCatalysis
dc.subjectCatalyst activity
dc.subjectChlorine compounds
dc.subjectLigands
dc.subjectMetal halides
dc.subjectPhosphorus compounds
dc.subjectQuantum chemistry
dc.subjectSynthesis (chemical)
dc.subjectArylations
dc.subjectThiazole derivatives
dc.subjectCatalytic mechanisms
dc.subjectHeteroarenes
dc.subjectPhosphine
dc.subjectSaccharinate
dc.subjectSteric properties
dc.subjectTertiary phosphines
dc.subjectPalladium compounds
dc.subject.scopusArylation; Polycondensation; Direct
dc.subject.wosChemistry, inorganic & nuclear
dc.titleSynthesis, structures and catalytic activity of Pd(II) saccharinate complexes with monophosphines in direct arylation of five-membered heteroarenes with aryl bromides
dc.typeArticle
dc.wos.quartileQ2
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

Files

License bundle

Now showing 1 - 1 of 1
Placeholder
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

İndeksli Yayınlar / Indexed Publications