Publication: D-fructose-derived acetonide as a green neutral organocatalyst for proficient one-pot and three-component preparation of 1,3-benzoxazine monomers
dc.contributor.author | Yıldırım, Ayhan | |
dc.contributor.author | Göker, Mustafa | |
dc.contributor.buuauthor | YILDIRIM, AYHAN | |
dc.contributor.buuauthor | Göker, Mustafa | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Kimya Bölümü | |
dc.contributor.orcid | 0000-0002-2328-9754 | |
dc.contributor.researcherid | W-8924-2019 | |
dc.contributor.researcherid | JIO-8136-2023 | |
dc.date.accessioned | 2024-07-08T09:40:13Z | |
dc.date.available | 2024-07-08T09:40:13Z | |
dc.date.issued | 2020-06-23 | |
dc.description.abstract | A series of 1,3-benzoxazine monomers were successfully synthesized by simple one-pot and three-component condensation of phenol, paraformaldehyde and varying types of primary aliphatic and aromatic amines in a molar ratio of 1 : 2 : 1 and in the presence of non-acidic 2,3;4,5-di-O-isopropylidene-beta-D-fructopyranose as an effective green carbohydrate based organocatalyst obtained from renewable feedstock. This multicomponent method provides a convenient fast approach for the construction of valuable 1,3-benzoxazine monomers (8 examples) with moderate to excellent yields. The chemical structures of the synthesized benzoxazines were confirmed by FTIR,H-1 NMR,C-13 NMR spectra and elemental analysis. | |
dc.identifier.doi | 10.1002/slct.202001911 | |
dc.identifier.endpage | 6977 | |
dc.identifier.issn | 2365-6549 | |
dc.identifier.issue | 23 | |
dc.identifier.startpage | 6971 | |
dc.identifier.uri | https://doi.org/10.1002/slct.202001911 | |
dc.identifier.uri | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202001911 | |
dc.identifier.uri | https://hdl.handle.net/11452/43034 | |
dc.identifier.volume | 5 | |
dc.identifier.wos | 000542282800015 | |
dc.indexed.wos | WOS.SCI | |
dc.language.iso | en | |
dc.publisher | Wiley-V C H Verlag | |
dc.relation.journal | Chemistryselect | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | Fully biobased benzoxazines | |
dc.subject | Ring-opening polymerization | |
dc.subject | Diamine-based benzoxazines | |
dc.subject | Catalyzed synthesis | |
dc.subject | Phenolic materials | |
dc.subject | Aldol reactions | |
dc.subject | Naphthoxazines | |
dc.subject | Condensation | |
dc.subject | Derivatives | |
dc.subject | Aldehydes | |
dc.subject | Benzoxazine | |
dc.subject | Monomer | |
dc.subject | Multicomponent reactions | |
dc.subject | Organocatalysis | |
dc.subject | Synthetic methods | |
dc.subject | Chemistry | |
dc.title | D-fructose-derived acetonide as a green neutral organocatalyst for proficient one-pot and three-component preparation of 1,3-benzoxazine monomers | |
dc.type | Article | |
dspace.entity.type | Publication | |
local.contributor.department | Fen Edebiyat Fakültesi/Kimya Bölümü | |
relation.isAuthorOfPublication | 4f8c3b28-d57b-40e9-bcd1-8a14308fbf1d | |
relation.isAuthorOfPublication.latestForDiscovery | 4f8c3b28-d57b-40e9-bcd1-8a14308fbf1d |