Yayın: Sustainable synthetic approaches using [C(16)Im][Oxa] as a flexible organocatalyst and DFT studies toward 3,4-dihydropyrimidinones and benzoxazines
Tarih
Kurum Yazarları
Yıldırım, Ayhan
Yazarlar
Kaya, Yunus
Danışman
Dil
Türü
Yayıncı:
Springer
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Özet
Easily accessible 1-hexadecyl-1H-imidazol-3-ium oxalate is highly efficient Bronsted type acidic catalyst for the selected multicomponent one-pot reactions. The short reaction times, easy workup procedures, and green metal-free conditions for the reactions make the protocols more advantageous. Further reactions proceeded smoothly in good to excellent yields with high purity. To investigate mechanism of the multicomponent reactions, DFT calculations were performed.
Açıklama
Kaynak:
Anahtar Kelimeler:
Konusu
Chemistry, Mannich reaction, Biginelli reaction, Organocatalysis, Green chemistry, Quantum chemical calculations, One-pot synthesis, Multicomponent biginelli reaction, Acidic ionic liquid, Solvent-free, Efficient synthesis, Pyrimidinone derivatives, Aromatic-aldehydes, Green synthesis, Catalyst, Dihydropyrimidinones
Alıntı
Yıldırım, A. ve Kaya, Y. (2017). ''Sustainable synthetic approaches using [C(16)Im][Oxa] as a flexible organocatalyst and DFT studies toward 3,4-dihydropyrimidinones and benzoxazines''. Monatshefte für Chemie, 148(6), 1085-1094.