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A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure

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dc.contributor.authorHamamcı, Sevim
dc.contributor.authorKazak, Canan
dc.contributor.buuauthorYılmaz, Veysel Turan
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-2849-3332
dc.contributor.researcheridL-7238-2018
dc.contributor.scopusid7006269202
dc.date.accessioned2021-12-09T11:53:18Z
dc.date.available2021-12-09T11:53:18Z
dc.date.issued2008-12-15
dc.description.abstractA new dinuclear silver(I)-saccharinato (sac) complex with acetonitrile (MeCN), [Ag-2(sac)(2)(MeCN)(2)](n) has been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. The silver(I) ions are doubly bridged by two sac ligands, leading to a short argentophilic contact of 2.9074(3) angstrom. Each silver(I) ion exhibits a square-planar coordination geometry including the Ag-Ag bonds. The individual dimeric molecules are extended into a two-dimensional layered structure by weak Ag center dot center dot center dot Csac(eta(2)) interactions of ca. 3.2 angstrom. These interactions were discussed and compared with those found in the first silver(I)-sac complex [Ag(sac)](n).
dc.identifier.citationYılmaz, V. T. vd. (2008). ''A novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure''. Journal of Organometallic Chemistry, 693(26), 3885-3888.
dc.identifier.endpage3888
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue26
dc.identifier.scopus2-s2.0-56349163759
dc.identifier.startpage3885
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2008.09.053
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0022328X08006165
dc.identifier.urihttp://hdl.handle.net/11452/23136
dc.identifier.volume693
dc.identifier.wos000261162900014
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherElsevier
dc.relation.collaborationYurt içi
dc.relation.journalJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemistry
dc.subjectAg⋯Ag interaction
dc.subjectAg⋯C interaction
dc.subjectCoordination polymer
dc.subjectSaccharinate
dc.subjectSquare-planar silver(I)
dc.subjectCrystal-structure
dc.subjectThermal-analysis
dc.subjectComplexes
dc.subjectPyrazine
dc.subjectLigands
dc.subjectFtir
dc.subjectABS resins
dc.subjectAcetonitrile
dc.subjectFlow interactions
dc.subjectPolymers
dc.subjectSilver compounds
dc.subjectSingle crystals
dc.subjectTwo dimensional
dc.subjectX ray diffraction analysis
dc.subjectCoordination polymer
dc.subjectCoordination polymers
dc.subjectDimeric molecules
dc.subjectDinuclear
dc.subjectElemental analyses
dc.subjectIR spectroscopies
dc.subjectIR spectrum
dc.subjectLayered structures
dc.subjectPlanar coordination geometries
dc.subjectSilvers (i)
dc.subjectSingle crystal x-ray diffractions
dc.subjectX-ray structures
dc.subjectCoordination reactions
dc.subject.scopusBenzisothiazole; Palladium; 2-Phenylpyridine
dc.subject.wosChemistry, inorganic & nuclear
dc.subject.wosChemistry, organic
dc.titleA novel two-dimensional silver(I) saccharinato coordination polymer constructed from weak Ag⋯C interactions: Synthesis, IR spectra and X-ray structure
dc.typeArticle
dc.wos.quartileQ2 (Chemistry, inorganic & nuclear)
dc.wos.quartileQ3 (Chemistry, organic)
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

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