One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones

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One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones

dc.contributor.buuauthor	Coşkun, Necdet
dc.contributor.buuauthor	Parlar, Aydın
dc.contributor.department	Fen Edebiyat Fakültesi
dc.contributor.department	Kimya Bölümü
dc.date.accessioned	2021-09-08T10:47:43Z
dc.date.available	2021-09-08T10:47:43Z
dc.date.issued	2005
dc.description.abstract	Aromatic aldehydes were reductively aminated to the corresponding secondary amines using NaBH4 in methanol in good yields. Amines were oxidized with H2O2-WO42- regioselectively to nitrones, the structures of which were easily determined by reacting them with hydroxylamine hydrochloride as well as by spectral means. The products of hydroxylaminolysis in ether proved to be the corresponding benzaldehyde oximes and benzyl or methyl hydroxylamine hydrochlorides.
dc.identifier.citation	Coşkun, N. ve Parlar, A. (2005). "One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones". Synthetic Communications, 35(18), 2445-2451.
dc.identifier.doi	10.1080/00397910500191169
dc.identifier.endpage	2451
dc.identifier.issn	0039-7911
dc.identifier.issue	18
dc.identifier.scopus	2-s2.0-25444525664
dc.identifier.startpage	2445
dc.identifier.uri	https://doi.org/10.1080/00397910500191169
dc.identifier.uri	https://www.tandfonline.com/doi/full/10.1080/00397910500191169
dc.identifier.uri	http://hdl.handle.net/11452/21779
dc.identifier.volume	35
dc.identifier.wos	000232104800012
dc.indexed.wos	SCIE
dc.language.iso	en
dc.publisher	Taylor & Francis
dc.relation.journal	Synthetic Communications
dc.relation.publicationcategory	Makale - Uluslararası Hakemli Dergi
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	Acyclic nitrone
dc.subject	Oxidation
dc.subject	Alkyl hydroxylamine hydrochloride
dc.subject	1,3-Dipolar cycloaddition
dc.subject	Oxidation
dc.subject	Imidazoline 3-oxides
dc.subject	Hydrogen-peroxide
dc.subject	Diastereoselective addition
dc.subject	Secondary-amines
dc.subject	Regio
dc.subject	Hydroxylamines
dc.subject	Chemistry
dc.subject.scopus	Nitrones; Cycloaddition Reactions; Hydroxylamines
dc.subject.wos	Chemistry, organic
dc.title	One-pot synthesis and hydrokylaminolysis of asymmetrical acyclic nitrones
dc.type	Article
dc.wos.quartile	Q3
dspace.entity.type	Publication
local.contributor.department	Fen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.at	Scopus
local.indexed.at	WOS