Publication: Synthesis and determination of the stability constant of mixed ligand complex of Y(III)
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Çam, Tülay
İrez, Gazi
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Asian Journal of Chemistry
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Abstract
In this study, the stability constants of a mixed ligand complex of the yttrium ion by using ethylenediaminetetraacetic acid (EDTA, H(2)A) as a primary ligand and 2,3-dihydroxy benzoic acid (2,3-DHBA, H3B) as a secondary ligand has been investigated. The stability constants of the binary and mixed ligand complexes have been determined by using a potentiometric method and the BEST computer program at 25 degrees C in a 0.1 M NaCl ionic medium. In addition, the identified complex by potentiometry was isolated as solids and the structural characteristics have been examined using IR, NMR, elemental analysis, AAS, ICP-OES, differential thermal analysis, thermogravimetric analysis and the conductivity method.
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Keywords
3-Dihydroxy benzoic acid, Yttrium, EDTA, Stability constant, Mixed ligand complex, Structural determination, Aqueous-solution, Acids, 9-coordinate, On, 8-coordinate, Chemistry
Citation
Çam, T. ve İrez, G. (2014). "Synthesis and determination of the stability constant of mixed ligand complex of Y(III)". Asian Journal of Chemistry, 26(8), 2429-2433.