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Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene

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Akademik Birimler

Kurum Yazarları

Coşkun, Necdet

Yazarlar

Erdem, İhsan
Gronert, Scott
Cabrera, Gabriel
Tapken, Marco

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Wiley-V C H

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Özet

The title compound exhibits a number of modes of reactivity toward nucleophiles/bases owing to the presence of several electrophilic and potentially nucleophilic sites in the molecule. We explored the reactions of 6-(chloromethyl)-6-methylfulvene with oxygen and nitrogen nucleophiles and bases as well as a carbon-based nucleophile (an enamine) and realized all possible reactivity modes predicted on the basis of electrophilic and nucleophilic positions in this compound.

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Chemistry, Fulvenes, Nucleophilic addition, Cycloaddition, 1,2-Dihydropentalene, Reaction mechanisms, Substituted fulvenes, Cyclopentadiene, Dimethylfulvene, Cycloaddition, 6,6-dimethylfulvene, Elimination, Precursors, Products, Acetone, System

Alıntı

Erden, İ. vd. (2017). ''Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene''. European Journal of Organic Chemistry, 20(2017), 2925-2931.

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