Publication: Synthesis, characterization and catalytic behavior of functionalized mesoporous SBA-15 with various organo-silanes
dc.contributor.author | Çıtak, Alime | |
dc.contributor.author | Öksüzoğlu, Ramis Mustafa | |
dc.contributor.buuauthor | Erdem, Beyhan | |
dc.contributor.buuauthor | Erdem, Sezer | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Fen Edebiyat Fakültesi | |
dc.contributor.department | Fizik Bölümü | |
dc.contributor.department | Kimya Bölümü | |
dc.contributor.researcherid | AAI-1238-2021 | |
dc.contributor.researcherid | AAI-1248-2021 | |
dc.contributor.scopusid | 14023997200 | |
dc.contributor.scopusid | 13805689400 | |
dc.date.accessioned | 2021-12-01T07:06:02Z | |
dc.date.available | 2021-12-01T07:06:02Z | |
dc.date.issued | 2012-03-01 | |
dc.description.abstract | Mesoporous silica SBA-15 has been synthesized and functionalized by one-step synthesis method to widen their various application possibilities. In this study, phenyltrimethoxysilane (PTMS), 3-mercapto-propyltrimethoxysilane (MPTMS) and trimethoxypropylsilane (TMPS) were used as silane precursors for the functionalization, and after treated with HCl solution, their catalytic activities were evaluated in the lactic acid-methanol esterification. The presence of anchoring of functional groups on SBA-15 was proved by XRD, FT-IR, BET surface area and pore size distributions. Good catalytic activity was observed especially for SBA-15-SO3H-MPTMS, and the catalytic activity order was determined as follows: SBA-15SO(3)H-MPTMS > SBA-15-TMPS > SBA-15-PTMS, which is directly associated with the surface area, pore size and pore volume. As compared with homogeneous catalyst, SBA-15-SO3H-MPTMS heterogeneous catalyst shows remarkable performance, such as separation, recovery and reusability. | |
dc.identifier.citation | Çıtak, A. vd. (2012). "Synthesis, characterization and catalytic behavior of functionalized mesoporous SBA-15 with various organo-silanes". Journal of Colloid and Interface Science, 369(1), 160-163. | |
dc.identifier.endpage | 163 | |
dc.identifier.issn | 0021-9797 | |
dc.identifier.issn | 1095-7103 | |
dc.identifier.issue | 1 | |
dc.identifier.pubmed | 22197058 | |
dc.identifier.scopus | 2-s2.0-84856092381 | |
dc.identifier.startpage | 160 | |
dc.identifier.uri | https://doi.org/10.1016/j.jcis.2011.11.070 | |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0021979711014470 | |
dc.identifier.uri | http://hdl.handle.net/11452/22911 | |
dc.identifier.volume | 369 | |
dc.identifier.wos | 000301320500021 | |
dc.indexed.wos | SCIE | |
dc.language.iso | en | |
dc.publisher | Academic Press Inc Elsevier Science | |
dc.relation.collaboration | Yurt içi | |
dc.relation.journal | Journal of Colloid and Interface Science | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | Chemistry | |
dc.subject | Sba-15 | |
dc.subject | Esterification | |
dc.subject | Functionalization | |
dc.subject | Mesoporous silica | |
dc.subject | Sulfonic-acid groups | |
dc.subject | Silica catalysts | |
dc.subject | Lactic-acid | |
dc.subject | Etherification | |
dc.subject | Nanoparticles | |
dc.subject | Resins | |
dc.subject | Esterification | |
dc.subject | Esters | |
dc.subject | Functional groups | |
dc.subject | Hydrochloric acid | |
dc.subject | Lactic acid | |
dc.subject | Mesoporous materials | |
dc.subject | Methanol | |
dc.subject | Pore size | |
dc.subject | Reusability | |
dc.subject | Silanes | |
dc.subject | Silica | |
dc.subject | 3-mercaptopropyltrimethoxysilane | |
dc.subject | Bet surface area | |
dc.subject | Catalytic behavior | |
dc.subject | Functionalized | |
dc.subject | Hcı solution | |
dc.subject | Heterogeneous catalyst | |
dc.subject | Homogeneous catalyst | |
dc.subject | Mesoporous Sba-15 | |
dc.subject | Mesoporous Silica | |
dc.subject | One step synthesis | |
dc.subject | Phenyltrimethoxysilanes | |
dc.subject | Pore volume | |
dc.subject | Sba-15 | |
dc.subject | Silane precursor | |
dc.subject | Surface area | |
dc.subject | Xrd | |
dc.subject | Catalyst activity | |
dc.subject.emtree | 3 mercaptopropyltrimethoxysilane | |
dc.subject.emtree | Functional group | |
dc.subject.emtree | Hydrochloric acid | |
dc.subject.emtree | Inorganic compound | |
dc.subject.emtree | Lactic acid | |
dc.subject.emtree | Methanol | |
dc.subject.emtree | Phenyltrimethoxysilane | |
dc.subject.emtree | Sba 15 | |
dc.subject.emtree | Silane derivative | |
dc.subject.emtree | Trimethoxypropylsilane | |
dc.subject.emtree | Unclassified drug | |
dc.subject.emtree | Article | |
dc.subject.emtree | Catalysis | |
dc.subject.emtree | Catalyst | |
dc.subject.emtree | Chemical analysis | |
dc.subject.emtree | Comparative study | |
dc.subject.emtree | Controlled study | |
dc.subject.emtree | Esterification | |
dc.subject.emtree | Infrared spectroscopy | |
dc.subject.emtree | Porosity | |
dc.subject.emtree | Priority journal | |
dc.subject.emtree | Surface property | |
dc.subject.emtree | Synthesis | |
dc.subject.emtree | X ray diffraction | |
dc.subject.scopus | Lipozyme; Enzymatic Interesterification; Structured Lipids | |
dc.subject.wos | Chemistry, physical | |
dc.title | Synthesis, characterization and catalytic behavior of functionalized mesoporous SBA-15 with various organo-silanes | |
dc.type | Article | |
dc.wos.quartile | Q2 | |
dspace.entity.type | Publication | |
local.contributor.department | Fen Edebiyat Fakültesi/Kimya Bölümü | |
local.contributor.department | Fen Edebiyat Fakültesi/Fizik Bölümü | |
local.indexed.at | Scopus | |
local.indexed.at | WOS |