Publication:
One-dimensional silver(I) 5,5-diethylbarbiturato coordination polymers with N-piperidineethanol and 1,3-bis(4-piperidyl)propane: Syntheses, crystal structures, spectroscopic and thermal properties

dc.contributor.authorBüyükgüngör, Orhan
dc.contributor.buuauthorYılmaz, Veysel Turan
dc.contributor.buuauthorSoyer, Eda
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-2849-3332
dc.contributor.researcheridL-7238-2018
dc.contributor.scopusid7006269202
dc.contributor.scopusid32267686800
dc.date.accessioned2022-01-14T07:11:55Z
dc.date.available2022-01-14T07:11:55Z
dc.date.issued2010-02-01
dc.description.abstractTwo new coordination polymers, [Ag(2)(barb)(pipet)](n) (1) and {Na(3)[Ag(2)(barb)(2)](pippr)center dot 2H(2)O}(n) (2) (where H(2)barb, pipet and Hpippr are 5,5-diethylbarbituric acid, N-piperidineethanol and 1,3-bis(4-piperidyl)propane, respectively) have been synthesized and characterized by elemental analysis, IR, thermal analysis and X-ray single-crystal diffraction techniques. Silver(I) ions in complexes 1 and 2 are bridged by barb dianions, leading to one-dimensional coordination polymers. In 1, the barb ligand acts as a tetradentate bridging ligand, while in 2 as a bidendate bridging ligand. The pipet ligand behaves as a bidentate chelating donor, whereas the pippr anion is not involved in coordination and remains as a counter-ion. The one-dimensional chains of 1 and 2 are further extended into supramolecular networks. Spectral and thermal analysis data for 1 and 2 are in agreement with the crystal structures.
dc.identifier.citationYılmaz, V. T. vd. (2010). "One-dimensional silver(I) 5,5-diethylbarbiturato coordination polymers with N-piperidineethanol and 1,3-bis(4-piperidyl)propane: Syntheses, crystal structures, spectroscopic and thermal properties". Polyhedron, 29(2), 920-924.
dc.identifier.endpage924
dc.identifier.issn0277-5387
dc.identifier.issue2
dc.identifier.scopus2-s2.0-73649144244
dc.identifier.startpage920
dc.identifier.urihttps://doi.org/10.1016/j.poly.2009.10.029
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S0277538709006949
dc.identifier.urihttp://hdl.handle.net/11452/24093
dc.identifier.volume29
dc.identifier.wos000275020700035
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherPergamon-Elsevier Science
dc.relation.bapF-2008/56
dc.relation.collaborationYurt içi
dc.relation.journalPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject5,5-Diethylbarbiturate
dc.subjectN-Piperidineethanol
dc.subject1,3-Bis(4-piperidyl)propane
dc.subjectCoordination polymers
dc.subjectSilver(I)
dc.subjectAntimicrobial activity
dc.subjectComplexes
dc.subjectCopper(II)
dc.subjectLigands
dc.subjectZinc
dc.subjectChemistry
dc.subjectCrystallography
dc.subject.scopusThiobarbituric Acid; Barbiturates; DMV
dc.subject.wosChemistry, inorganic & nuclear
dc.subject.wosCrystallography
dc.titleOne-dimensional silver(I) 5,5-diethylbarbiturato coordination polymers with N-piperidineethanol and 1,3-bis(4-piperidyl)propane: Syntheses, crystal structures, spectroscopic and thermal properties
dc.typeArticle
dc.wos.quartileQ2
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

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