Publication:
Search for a nonelectrocyclic cyclization of nitrosostyrene: Rearrangements of Michael adducts from DMAD and alpha-dialkylamino oximes

Simple item page
dc.contributor.buuauthorCoşkun, Necdet
dc.contributor.buuauthorArıkan, Nevin
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.researcheridAAH-6337-2021
dc.contributor.researcheridB-1200-2012
dc.contributor.scopusid7004177880
dc.contributor.scopusid6603961440
dc.date.accessioned2023-04-03T07:40:44Z
dc.date.available2023-04-03T07:40:44Z
dc.date.issued2003
dc.description.abstractThe aza-Claisen rearrangement product of the Michael adducts 2 from alpha-dialkylaminoacetophenone oximes and DMAD underwent fragmentation to give dialkylaminomaleate, and benzonitrile at reflux in acetonitrile. The fragmentation was assumed to proceed through an unstable 4H-1,2-oxazete 6. The same reaction performed at room temperature, in addition to the nitrile and maleate, gave the corresponding 2-(2-dialkylamino-1-phenylethylideneaminooxy)-but-2-enedioic acid dimethyl esters 8 and 9. Compounds 9 isomerized to 8 on heating in acetonitrile.
dc.identifier.citationCoşkun, N. ve Arıkan, N. (2003). “Search for a nonelectrocyclic cyclization of nitrosostyrene: Rearrangements of Michael adducts from DMAD and alpha-dialkylamino oximes”. Turkish Journal of Chemistry, 27(1), 15-20.
dc.identifier.endpage20
dc.identifier.issn1010-7614
dc.identifier.issue1
dc.identifier.scopus2-s2.0-0037219007
dc.identifier.startpage15
dc.identifier.urihttps://journals.tubitak.gov.tr/chem/vol27/iss1/3/
dc.identifier.urihttp://hdl.handle.net/11452/32138
dc.identifier.volume27
dc.identifier.wos000181586900003
dc.indexed.scopusScopus
dc.indexed.trdizinTrDizin
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherTÜBİTAK
dc.relation.bapNo 2001/2
dc.relation.journalTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectChemistry
dc.subjectEngineering
dc.subjectN-oxides
dc.subject.emtreeAnalytical parameters
dc.subject.emtreeArticle
dc.subject.emtreeChemical procedures
dc.subject.emtreeCyclization
dc.subject.emtreeFragmentation reaction
dc.subject.emtreeIsomerism
dc.subject.emtreeRoom temperature
dc.subject.emtreeAcetonitrile
dc.subject.emtreeAmino oxime
dc.subject.emtreeBenzonitrile
dc.subject.emtreeEster derivative
dc.subject.emtreeMaleic acid
dc.subject.emtreeMaleic acid derivative
dc.subject.emtreeNitrile
dc.subject.emtreeNitrosostyrene
dc.subject.emtreeOxime derivative
dc.subject.emtreeStyrene
dc.subject.emtreeUnclassified drug
dc.subject.scopusIsonitrosoacetophenone; Oximes; Acetaldoxime
dc.subject.wosChemistry, multidisciplinary
dc.subject.wosEngineering, chemical
dc.titleSearch for a nonelectrocyclic cyclization of nitrosostyrene: Rearrangements of Michael adducts from DMAD and alpha-dialkylamino oximes
dc.typeArticle
dc.wos.quartileN/A
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atTrDizin
local.indexed.atWOS
local.indexed.atScopus

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
Coşkun_Arıkan_2003.pdf
Size:
182.89 KB
Format:
Adobe Portable Document Format
Description:
Download

License bundle

Now showing 1 - 1 of 1
Placeholder
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

İndeksli Yayınlar / Indexed Publications