Publication:
Principal component analysis and cluster analysis for the characterisation of marbles by capillary electrophoresis

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dc.contributor.buuauthorYücel, Yasin
dc.contributor.buuauthorDemir, Cevdet
dc.contributor.departmentFen Edebiyat Fakültesi
dc.contributor.departmentKimya Bölümü
dc.contributor.orcid0000-0002-8572-4213
dc.contributor.orcid0000-0003-1508-0181
dc.contributor.orcid0000-0002-9381-0410
dc.contributor.researcheridABA-2005-2020
dc.contributor.researcheridG-1507-2019
dc.contributor.scopusid6603779481
dc.contributor.scopusid7003565902
dc.date.accessioned2022-03-30T08:38:46Z
dc.date.available2022-03-30T08:38:46Z
dc.date.issued2004-05-28
dc.description.abstractChemical characterisation has been carried out on 25 quarry marbles collected from Marmara, Aegean and Thrace regions of Turkey. Ten elements were determined by capillary electrophoresis (CE). Principal component analysis and cluster analysis techniques were Utilised to define grouping of different marble samples. These techniques showed that the analysed marbles were differentiable mainly by provenance. Experimental conditions such as pH. applied voltage and concentration of alpha-hydroxyisobutyric acid (HIBA) were optimised to achieve the best separation of metal ions using central composite design. The optimum pH 3.7, applied voltage 15 kV and concentration of HIBA 10 mM were found to provide the best separation for all metal ions investigated.
dc.identifier.citationYücel, Y. ve Demir, C. (2004). “Principal component analysis and cluster analysis for the characterisation of marbles by capillary electrophoresis”. Talanta, 63(2), 451-459.
dc.identifier.endpage459
dc.identifier.issn0039-9140
dc.identifier.issnhttps://www.sciencedirect.com/science/article/pii/S0039914003006738
dc.identifier.issue2
dc.identifier.pubmed18969453
dc.identifier.scopus2-s2.0-2142707166
dc.identifier.startpage451
dc.identifier.urihttps://doi.org/10.1016/j.talanta.2003.11.014
dc.identifier.urihttp://hdl.handle.net/11452/25434
dc.identifier.volume63
dc.identifier.wos000221434300034
dc.indexed.wosSCIE
dc.language.isoen
dc.publisherElsevier
dc.relation.bap2000/17
dc.relation.journalTalanta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectChemistry
dc.subjectCapillary electrophoresis (CE)
dc.subjectPrincipal component analysis
dc.subjectCluster analysis
dc.subjectMarbles
dc.subjectMetal ions
dc.subjectCharacterisation
dc.subjectInorganic metal-cations
dc.subjectAlkaline-earth
dc.subjectZone-electrophoresis
dc.subjectSeparation
dc.subjectOptimization
dc.subjectIons
dc.subjectChromatography
dc.subjectDifferentiation
dc.subjectElectrolyte
dc.subjectAmmonium
dc.subjectElectrophoresis
dc.subjectpH effects
dc.subjectMarble
dc.subject.emtreeAcidity
dc.subject.emtreeArticle
dc.subject.emtreeCapillary electrophoresis
dc.subject.emtreeCluster analysis
dc.subject.emtreeElectric potential
dc.subject.emtreePrincipal component analysis
dc.subject.emtreeSeparation technique
dc.subject.emtree2 hydroxy 2 methylpropionic acid
dc.subject.emtreeIsobutyric acid
dc.subject.emtreeMetal ion
dc.subject.emtreeUnclassified drug
dc.subject.scopusCapillary Electrophoresis; Carboxylic Acids; Wines
dc.subject.wosChemistry, analytical
dc.titlePrincipal component analysis and cluster analysis for the characterisation of marbles by capillary electrophoresis
dc.typeArticle
dc.wos.quartileQ1
dspace.entity.typePublication
local.contributor.departmentFen Edebiyat Fakültesi/Kimya Bölümü
local.indexed.atScopus
local.indexed.atWOS

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