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New alkoxyzinc salts mediated chemoselective transesterification reactions

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Coşkun, Necdet
Er, Mustafa

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A new chemoselective method for the transesterification of alkyl esters in the presence of in situ formed alkoxyzinc salts was developed. Electron-rich esters are less reactive than electron poor ones and this is the basis for the chemoselectivity of the reaction. Suggested mechanisms of the transesterification reactions are discussed.

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Chemistry, Engineering, Chemoselective transesterification, Zinc bromide, Zinc acetate, Alkoxyzinc bromide, Alkoxyzinc acetate, Ring-opening reactions, Beta-ketoesters, Esters, Acid, Efficient, Catalyst

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Coşkun, N. ve Er, M. (2005). "New alkoxyzinc salts mediated chemoselective transesterification reactions". Turkish Journal of Chemistry, 29(5), 455-461.

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