One-dimensionally hydrogen-bonded silver(I) saccharinate complexes with N-(2-aminoethyl)piperidine and N-(2-hydroxyethyl)piperidine: Synthesis, crystal structures, FTIR and thermal studies

Simple item page
dc.contributor.authorHamamcı, Sevim
dc.contributor.authorBüyükgüngör, Orhan
dc.contributor.buuauthorYılmaz, Veysel Turan
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.contributor.orcid0000-0002-2849-3332tr_TR
dc.contributor.researcheridL-7238-2018tr_TR
dc.contributor.scopusid7006269202tr_TR
dc.date.accessioned2024-04-05T06:37:46Z
dc.date.available2024-04-05T06:37:46Z
dc.date.issued2008-02
dc.description.abstractTwo new complexes [Ag(sac)(aepip)] (1) and [Ag(sac)(hepip)] (2) have been obtained by the reaction of AgNO3 with Na(sac)center dot 2H(2)O (sac = saccharinate) in the presence of N-(2-aminoethyl)piperidine (aepip) and N-(2-hydroxyethyl)piperidine (hepip), and characterized by elemental analysis, IR spectroscopy, thermal analysis and single crystal X-ray diffraction. Complexes 1 and 2 crystallize in the monoclinic space group C2 and triclinic space group P (1) over bar, respectively. In both complexes, silver(I) is tricoordinated. The sac ligand is N-coordinated, while aepip and hepip behave as N-N and N-O bidentate chelating ligands, respectively. The pip rings of both aepip amd hepip ligands adopt typical 'chair' conformation. The individual molecules are linked into one-dimensional chains by two N-H center dot center dot center dot O hydrogen bonds in 1, and one O-H center dot center dot center dot O hydrogen bond in 2. TG-DTG curves illustrated that the endothermic elimination of aepip and hepip ligands takes place in the early stages of thermal decomposition, while that of the sac moiety occurs exothermically at higher temperatures to give metallic silver.en_US
dc.identifier.citationHamamcı, S. vd. (2008). "One-dimensionally hydrogen-bonded silver(I) saccharinate complexes with N-(2-aminoethyl)piperidine and N-(2-hydroxyethyl)piperidine: Synthesis, crystal structures, FTIR and thermal studies". Zeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences, 63(2), 139-142.en_US
dc.identifier.doihttps://doi.org/10.1515/znb-2008-0205
dc.identifier.eissn1865-7117
dc.identifier.endpage142tr_TR
dc.identifier.issn0932-0776
dc.identifier.issue2tr_TR
dc.identifier.scopus2-s2.0-39449132571tr_TR
dc.identifier.startpage139tr_TR
dc.identifier.urihttps://www.degruyter.com/document/doi/10.1515/znb-2008-0205/htmlen_US
dc.identifier.urihttps://hdl.handle.net/11452/41055
dc.identifier.volume63tr_TR
dc.identifier.wos000253003200005tr_TR
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherWalter de Gruyteren_US
dc.relation.collaborationYurt içitr_TR
dc.relation.journalZeitschrift fur Naturforschung Section B-A Journal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectChemistryen_US
dc.subjectCrystal structureen_US
dc.subjectSaccharinate complexen_US
dc.subjectSilver(i)en_US
dc.subjectComplexationen_US
dc.subjectCrystal structureen_US
dc.subjectDecompositionen_US
dc.subjectFourier transform infrared spectroscopyen_US
dc.subjectHydrogen bondsen_US
dc.subjectLigandsen_US
dc.subjectSilver metallographyen_US
dc.subjectSingle crystalsen_US
dc.subjectSodium compoundsen_US
dc.subjectSodium metallographyen_US
dc.subjectSynthesis (chemical)en_US
dc.subjectThermoanalysisen_US
dc.subjectChelating ligandsen_US
dc.subjectMetallic silveren_US
dc.subjectMonoclinic space groupsen_US
dc.subjectOne-dimensional chainsen_US
dc.subjectSaccharinateen_US
dc.subjectSilvers (i)en_US
dc.subjectSingle crystal x-ray diffractionen_US
dc.subjectTriclinic space groupen_US
dc.subjectSilver compoundsen_US
dc.subjectSpectraen_US
dc.subject.scopusComplex; Palladium; 2-Phenylpyridineen_US
dc.subject.wosChemistry, inorganic & nuclearen_US
dc.subject.wosChemistry, organicen_US
dc.titleOne-dimensionally hydrogen-bonded silver(I) saccharinate complexes with N-(2-aminoethyl)piperidine and N-(2-hydroxyethyl)piperidine: Synthesis, crystal structures, FTIR and thermal studiesen_US
dc.typeArticleen_US
dc.wos.quartileQ3 (Chemistry, inorganic & nuclear)en_US
dc.wos.quartileQ4 (Chemistry, organic)en_US

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Hamamcı_vd_2008.pdf
Size:
221.47 KB
Format:
Adobe Portable Document Format
Download
License bundle
Now showing 1 - 1 of 1
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Web of Science