Synthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazole

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dc.contributor.authorGümüş, Sedat
dc.contributor.buuauthorGüney, Emel
dc.contributor.buuauthorKaya, Yunus
dc.contributor.buuauthorYılmaz, Veysel T.
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.contributor.orcid0000-0002-2849-3332tr_TR
dc.contributor.researcheridL-7238-2018tr_TR
dc.contributor.scopusid25027291500tr_TR
dc.contributor.scopusid35181446100tr_TR
dc.contributor.scopusid7006269202tr_TR
dc.date.accessioned2021-12-24T12:44:07Z
dc.date.available2021-12-24T12:44:07Z
dc.date.issued2011-09
dc.description.abstractNew palladium(II) and platinum(II) complexes of saccharinate (sac) with 2-(2-pyridyl)benzimidazole (pybim) have been synthesized and characterized by elemental analysis and spectroscopic techniques. From the experimental studies, these complexes were formulated as [Pd(pybim)(sac)(2)] (1), and [Pt(pybim)(sac)(2)]center dot 4H(2)O (2). The ground-state geometries of both complexes were optimized using density functional theory (DFT) methods at the B3LYP level. A bidentate pybim ligand together with two N-coordinated sac ligands form the square-planar MN4 coordination geometry around the palladium(II) and platinum(II) ions. The calculated IR and UV-vis spectral data have been correlated to the experimental results. Thermal analysis data support the molecular structures of both complexes.en_US
dc.identifier.citationGüney, E. vd. (2011) ''Synthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazole''. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 79(5), 1171-1178.en_US
dc.identifier.endpage1178tr_TR
dc.identifier.issn1386-1425
dc.identifier.issn1873-3557
dc.identifier.issue5tr_TR
dc.identifier.pubmed21665528tr_TR
dc.identifier.scopus2-s2.0-79960266565tr_TR
dc.identifier.startpage1171tr_TR
dc.identifier.urihttps://doi.org/10.1016/j.saa.2011.04.038
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S138614251100285X
dc.identifier.urihttp://hdl.handle.net/11452/23614
dc.identifier.volume79tr_TR
dc.identifier.wos000293363000047tr_TR
dc.indexed.pubmedPubmeden_US
dc.indexed.scopusScopusen_US
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Scienceen_US
dc.relation.collaborationYurt içitr_TR
dc.relation.journalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSpectroscopyen_US
dc.subjectSaccharinateen_US
dc.subject2-(2-Pyridyl)benzimidazoleen_US
dc.subjectPalladium(II)en_US
dc.subjectPlatinum(II)en_US
dc.subjectDFTen_US
dc.subjectPT(II)en_US
dc.subjectZINC(II)en_US
dc.subjectVibrational frequenciesen_US
dc.subjectCrystal-structuresen_US
dc.subjectLigandsen_US
dc.subjectBenzimidazoleen_US
dc.subjectFluorescenten_US
dc.subjectChemistryen_US
dc.subjectPolymersen_US
dc.subjectDensity functional theoryen_US
dc.subjectLigandsen_US
dc.subjectPlatinumen_US
dc.subjectPlatinum compoundsen_US
dc.subjectSpectroscopic analysisen_US
dc.subjectThermoanalysisen_US
dc.subjectBenzimidazolesen_US
dc.subjectCoordination geometryen_US
dc.subjectData supporten_US
dc.subjectDensity functional theory methodsen_US
dc.subjectExperimental studiesen_US
dc.subjectGround state geometryen_US
dc.subjectSaccharinateen_US
dc.subjectSpectral dataen_US
dc.subjectSpectroscopic techniqueen_US
dc.subjectPalladium compoundsen_US
dc.subject.emtree2 (2' pyridyl)benzimidazoleen_US
dc.subject.emtree2-(2'-pyridyl)benzimidazoleen_US
dc.subject.emtreeBenzimidazole derivativeen_US
dc.subject.emtreeOrganometallic compounden_US
dc.subject.emtreePalladiumen_US
dc.subject.emtreePlatinumen_US
dc.subject.emtreeArticleen_US
dc.subject.emtreeChemical structureen_US
dc.subject.emtreeChemistryen_US
dc.subject.emtreeInfrared spectrophotometryen_US
dc.subject.emtreeMetabolismen_US
dc.subject.emtreeNuclear magnetic resonance spectroscopyen_US
dc.subject.emtreeSynthesisen_US
dc.subject.emtreeTheoretical modelen_US
dc.subject.emtreeX ray crystallographyen_US
dc.subject.meshBenzimidazolesen_US
dc.subject.meshCrystallography, X-rayen_US
dc.subject.meshMagnetic resonance spectroscopyen_US
dc.subject.meshModels, molecularen_US
dc.subject.meshModels, theoreticalen_US
dc.subject.meshMolecular structureen_US
dc.subject.meshOrganometallic compoundsen_US
dc.subject.meshPalladiumen_US
dc.subject.meshPlatinumen_US
dc.subject.meshSpectrophotometry, infrareden_US
dc.subject.scopusBenzisothiazole; Palladium; 2-Phenylpyridineen_US
dc.subject.wosSpectroscopyen_US
dc.titleSynthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazoleen_US
dc.typeArticle
dc.wos.quartileQ2en_US

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