Synthesis and complex formation of some novel vic-dioxime derivatives of hydrazones

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Date

2005

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Publisher

TÜBİTAK

Abstract

Three novel vic-dioxime compounds and their transition metal complexes were synthesized for the first time. These ligands are anti-glyoximehydrazine (GH(2)),:.,anti-2-pyridinealdehydeglyoxime hydrazone (PyGH(2)) and anti-2-furanearboxaldehydeglyoxime h hydrazone (FGH(2)). The synthesized antiglyoximehydrazine was reacted with 2-pyridinealdehyde or 2-furancarboxaldehyde to obtain the PyGH2 and FGH(2)ligands. Mononuclear complexes of these ligands with a metal-ligand ratio of 1:2 were prepared with Ni(II), Co(II) and Cu(II) ions. The structures of the ligands and complexes were determined by H-1 n.m.r, i.r spectroscopy and elemental analytical techniques.

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Keywords

Vic-dioximes, Metal complexes, Hydrazone compounds, Glyoximes, Nickel(II), Palladium(II), Cobalt(II), Copper(II), Reagents, Chemistry, Engineering

Citation

Sarıkavaklı, N. ve Irez, G. (2005). "Synthesis and complex formation of some novel vic-dioxime derivatives of hydrazones". Turkish Journal of Chemistry, 29(1), 107-115.