A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: Synthesis, crystal structure, spectroscopic and thermal characterization

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dc.contributor.authorÇolak, Alper Tolga
dc.contributor.authorHökelek, Tuncer
dc.contributor.authorÇaylak, Nagihan
dc.contributor.buuauthorİrez, Gazi
dc.contributor.buuauthorGençkal, Hasene Mutlu
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Anabilim Dalı.tr_TR
dc.contributor.orcid0000-0002-0026-7755tr_TR
dc.contributor.researcheridAAH-2888-2021tr_TR
dc.contributor.scopusid6602755323tr_TR
dc.contributor.scopusid57212275330tr_TR
dc.date.accessioned2021-12-09T11:01:34Z
dc.date.available2021-12-09T11:01:34Z
dc.date.issued2009
dc.description.abstractA cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.en_US
dc.description.sponsorshipDumlupınar Üniversitesi (2007/14)tr_TR
dc.identifier.citationÇolak, A. T. vd. (2009). "A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: Synthesis, crystal structure, spectroscopic and thermal characterization". Journal of Coordination Chemistry, 62(6), 1005-1014.en_US
dc.identifier.endpage1014tr_TR
dc.identifier.issn0095-8972
dc.identifier.issue6tr_TR
dc.identifier.scopus2-s2.0-61649103142tr_TR
dc.identifier.startpage1005tr_TR
dc.identifier.urihttps://doi.org/10.1080/00958970802345831
dc.identifier.urihttps://www.tandfonline.com/doi/full/10.1080/00958970802345831
dc.identifier.urihttp://hdl.handle.net/11452/23129
dc.identifier.volume62tr_TR
dc.identifier.wos000262512000015tr_TR
dc.indexed.scopusScopusen_US
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.relation.bap2003/98tr_TR
dc.relation.collaborationYurt içitr_TR
dc.relation.journalJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.relation.tubitakDPT/TBAG1tr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1-Phenyl-1,2-propanedione-2-oximeen_US
dc.subject2-Aminobenzylamineen_US
dc.subjectAmine-imine-oximeen_US
dc.subjectCobalt(III)en_US
dc.subjectTransition-metal-complexesen_US
dc.subjectNickel(II)en_US
dc.subjectCobalt(II)en_US
dc.subjectDioximeen_US
dc.subjectChemistryen_US
dc.subject.scopusSpeciation (Chemistry); Chemical Models; Osmolar Concentrationen_US
dc.subject.wosChemistry, inorganic & nuclearen_US
dc.titleA Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: Synthesis, crystal structure, spectroscopic and thermal characterizationen_US
dc.typeArticle
dc.wos.quartileQ3en_US

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