2-(Naphthalen-2-yl)-1,2,3,4-tetrahydroquinazoline-2-carbaldehy de oxime and Co(III) and Ni(II) complexes of tridentate ligand containing oxime, imine and amine donor groups: Syntheses, characterisation and thermal properties

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dc.contributor.buuauthorSırıkçı, Gökhan
dc.contributor.buuauthorİrez, Gazi
dc.contributor.buuauthorGençkal, Hasene Mutlu
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.contributor.orcid0000-0002-0026-7755tr_TR
dc.contributor.orcid0000-0003-3690-7002tr_TR
dc.contributor.researcheridAAH-2888-2021tr_TR
dc.date.accessioned2022-05-09T06:26:20Z
dc.date.available2022-05-09T06:26:20Z
dc.date.issued2012
dc.description.abstractA novel 1,2,3,4-tetrahydroquinazoline oxime was synthesised from a condensation reaction of 2-(naphthalen-2-yl)-2-oxoacetaldehyde oxime with 2-aminobenzylamine. Subsequently, alpha-imine oxime complexes of this compound that formed with Co(III) and Ni(II) metal ions were obtained. All structures were characterised by spectral methods (FT-IR, NMR, AAS, mass), elemental analysis, thermal analyses, magnetic susceptibility and molar conductivity. The analyses confirmed the following molecular formulae: [Co(L)(2)]Cl center dot C-2 H5OH center dot 0,5H(2)O and [Ni(HL)(2)]Cl-2. The Co(III) complex is diamagnetic. Magnetic susceptibility measurements revealed octahedral geometry for the Co(III) and Ni(II) complexes. In the complexes, the chloride ion was found to be noncoordinated to the metal ions as confirmed by conductivity measurements. The NMR spectra of the Co(III) complex confirmed the presence ofethanol in the Co(III) complex. The experimental results of TG-DTA showed that the Co(III) complex contained ethanol and crystal water in the first two stages. The end of the thermal decomposition of the complexes yielded a final product of a metal oxide.en_US
dc.identifier.citationSırıkçı, G. vd. (2012). "2-(Naphthalen-2-yl)-1,2,3,4-tetrahydroquinazoline-2-carbaldehy de oxime and Co(III) and Ni(II) complexes of tridentate ligand containing oxime, imine and amine donor groups: Syntheses, characterisation and thermal properties". Acta Chimica Slovenica, 59(4), 904-911.en_US
dc.identifier.endpage911tr_TR
dc.identifier.issn1318-0207
dc.identifier.issn1580-3155
dc.identifier.issue4tr_TR
dc.identifier.pubmed24061374tr_TR
dc.identifier.startpage904tr_TR
dc.identifier.urihttps://pubmed.ncbi.nlm.nih.gov/24061374/
dc.identifier.urihttp://hdl.handle.net/11452/26304
dc.identifier.volume59tr_TR
dc.identifier.wos000313199100023tr_TR
dc.indexed.pubmedPubMeden_US
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherSlovensko Kemijsko Drustvosl
dc.relation.bap2006/66tr_TR
dc.relation.journalActa Chimica Slovenicaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.relation.tubitak106T371tr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChemistryen_US
dc.subject2-(naphthalen-2-yl)-1,2,3,4-tetrahydroquinazoline-2-carbaldehyde oximeen_US
dc.subjectAmine-imine-oximeen_US
dc.subjectAlpha-imine oximeen_US
dc.subjectCo(III) complexen_US
dc.subjectNi(II) complexen_US
dc.subjectPotential anticancer agentsen_US
dc.subjectRing-chain tautomerismen_US
dc.subjectSolvent-free synthesisen_US
dc.subjectTetrahydroquinazoline analogsen_US
dc.subjectDerivativesen_US
dc.subject1,2,3,4-tetrahydroquinazolineen_US
dc.subjectEfficienten_US
dc.subject.wosChemistry, multidisciplinaryen_US
dc.title2-(Naphthalen-2-yl)-1,2,3,4-tetrahydroquinazoline-2-carbaldehy de oxime and Co(III) and Ni(II) complexes of tridentate ligand containing oxime, imine and amine donor groups: Syntheses, characterisation and thermal propertiesen_US
dc.typeArticle
dc.wos.quartileQ3en_US

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