Principal component analysis and cluster analysis for the characterisation of marbles by capillary electrophoresis

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dc.contributor.buuauthorYücel, Yasin
dc.contributor.buuauthorDemir, Cevdet
dc.contributor.departmentUludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.tr_TR
dc.contributor.orcid0000-0002-8572-4213tr_TR
dc.contributor.orcid0000-0003-1508-0181tr_TR
dc.contributor.orcid0000-0002-9381-0410tr_TR
dc.contributor.researcheridABA-2005-2020tr_TR
dc.contributor.researcheridG-1507-2019tr_TR
dc.contributor.scopusid6603779481tr_TR
dc.contributor.scopusid7003565902tr_TR
dc.date.accessioned2022-03-30T08:38:46Z
dc.date.available2022-03-30T08:38:46Z
dc.date.issued2004-05-28
dc.description.abstractChemical characterisation has been carried out on 25 quarry marbles collected from Marmara, Aegean and Thrace regions of Turkey. Ten elements were determined by capillary electrophoresis (CE). Principal component analysis and cluster analysis techniques were Utilised to define grouping of different marble samples. These techniques showed that the analysed marbles were differentiable mainly by provenance. Experimental conditions such as pH. applied voltage and concentration of alpha-hydroxyisobutyric acid (HIBA) were optimised to achieve the best separation of metal ions using central composite design. The optimum pH 3.7, applied voltage 15 kV and concentration of HIBA 10 mM were found to provide the best separation for all metal ions investigated.en_US
dc.identifier.citationYücel, Y. ve Demir, C. (2004). “Principal component analysis and cluster analysis for the characterisation of marbles by capillary electrophoresis”. Talanta, 63(2), 451-459.en_US
dc.identifier.endpage459tr_TR
dc.identifier.issn0039-9140
dc.identifier.issnhttps://www.sciencedirect.com/science/article/pii/S0039914003006738
dc.identifier.issue2tr_TR
dc.identifier.pubmed18969453tr_TR
dc.identifier.scopus2-s2.0-2142707166tr_TR
dc.identifier.startpage451tr_TR
dc.identifier.urihttps://doi.org/10.1016/j.talanta.2003.11.014
dc.identifier.urihttp://hdl.handle.net/11452/25434
dc.identifier.volume63tr_TR
dc.identifier.wos000221434300034tr_TR
dc.indexed.pubmedPubMeden_US
dc.indexed.scopusScopusen_US
dc.indexed.wosSCIEen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.bap2000/17tr_TR
dc.relation.journalTalantaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergitr_TR
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChemistryen_US
dc.subjectCapillary electrophoresis (CE)en_US
dc.subjectPrincipal component analysisen_US
dc.subjectCluster analysisen_US
dc.subjectMarblesen_US
dc.subjectMetal ionsen_US
dc.subjectCharacterisationen_US
dc.subjectInorganic metal-cationsen_US
dc.subjectAlkaline-earthen_US
dc.subjectZone-electrophoresisen_US
dc.subjectSeparationen_US
dc.subjectOptimizationen_US
dc.subjectIonsen_US
dc.subjectChromatographyen_US
dc.subjectDifferentiationen_US
dc.subjectElectrolyteen_US
dc.subjectAmmoniumen_US
dc.subjectElectrophoresisen_US
dc.subjectpH effectsen_US
dc.subjectMarbleen_US
dc.subject.emtreeAcidityen_US
dc.subject.emtreeArticleen_US
dc.subject.emtreeCapillary electrophoresisen_US
dc.subject.emtreeCluster analysisen_US
dc.subject.emtreeElectric potentialen_US
dc.subject.emtreePrincipal component analysisen_US
dc.subject.emtreeSeparation techniqueen_US
dc.subject.emtree2 hydroxy 2 methylpropionic aciden_US
dc.subject.emtreeIsobutyric aciden_US
dc.subject.emtreeMetal ionen_US
dc.subject.emtreeUnclassified drugen_US
dc.subject.scopusCapillary Electrophoresis; Carboxylic Acids; Winesen_US
dc.subject.wosChemistry, analyticalen_US
dc.titlePrincipal component analysis and cluster analysis for the characterisation of marbles by capillary electrophoresisen_US
dc.typeArticle
dc.wos.quartileQ1en_US

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