Büyükgüngör, Orhan2022-02-082022-02-082011Kaya, Y. vd. (2011). ''A novel reaction of α-carbonyl oxime and amido alcohol: Synthesis, characterization, crystal structure, and thermal studies of an amido alcohol, a new oximino alcohol ligand, and its metal complexes''. Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 41(7), 754-762.1553-31741553-3182https://doi.org/10.1080/15533174.2011.591300https://www.tandfonline.com/doi/full/10.1080/15533174.2011.591300http://hdl.handle.net/11452/24378In this study, a novel reaction was observed between isonitrosoacetophenone and 1-phenylethanol amine. Acetophenone was used as a starting material to synthesize isonitrosoacetophenone by reaction of acetophenone with n-butyl nitrite in the presence of sodium ethoxide and to synthesize 1-phenylethanol amine by reduction of isonitrosoacetophenone with LiAlH4 in diethyl ether. When the isonitrosoacetophenone reacted with 1-phenylethanol amine, (3E)-3-aza-5-(hydroxyimino)1,4-diphenylpent-3-en-1-ol monohydrate, a new oximino alcohol ligand and amido alcohol were obtained as associated product interestingly. Four complexes were prepared by treatment of oximino alcohol with metal salts such as Cu-II, Ni-II, Zn-II, and Co-II. Amido alcohol was characterized by single-crystal x-ray diffraction, and all complexes were characterized by using spectroscopic techniques and thermogravimetric analysis (TGA).eninfo:eu-repo/semantics/closedAccessChemistryScience & technology - other topicsOximino alcoholReductionAmido alcoholSchiff-base ligandsCu(II)Copper(II)Co(II)Ni(II)Nickel(II)Cobalt(II)Zinc(II)DioximeArticle0002963186000072-s2.0-80051735017754762417Chemistry, inorganic & nuclearNanoscience & nanotechnologySalophen; Schiff Bases; Elemental Analyses