Çolak, Alper TolgaHökelek, TuncerÇaylak, Nagihan2021-12-092021-12-092009Çolak, A. T. vd. (2009). "A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: Synthesis, crystal structure, spectroscopic and thermal characterization". Journal of Coordination Chemistry, 62(6), 1005-1014.0095-8972https://doi.org/10.1080/00958970802345831https://www.tandfonline.com/doi/full/10.1080/00958970802345831http://hdl.handle.net/11452/23129A cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.eninfo:eu-repo/semantics/closedAccess1-Phenyl-1,2-propanedione-2-oxime2-AminobenzylamineAmine-imine-oximeCobalt(III)Transition-metal-complexesNickel(II)Cobalt(II)DioximeChemistryArticle0002625120000152-s2.0-6164910314210051014626Chemistry, inorganic & nuclearSpeciation (Chemistry); Chemical Models; Osmolar Concentration