Büyükgüngör, Orhan2024-02-142024-02-142014-05-14Kaya, Y. vd. (2014). "A combined experimental and theoretical investigation of a new imineoxime and its palladium(II) and platinum(II) complexes: Synthesis, structural characterization and spectroscopic properties". Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 133, 93-101.1386-1425https://doi.org/10.1016/j.saa.2014.05.055https://www.sciencedirect.com/science/article/pii/S138614251400835X?via%3Dihubhttps://hdl.handle.net/11452/39682A new imineoxime compound {(1E,2E)-(2-hydroxy-ethylimino)-naphthalene-2yl-ethanal oxime (heineoH)} and its palladium(II) and platinum(II) complexes ([M(heineo)(2)]) have been synthesized and characterized by IR, NMR, UV-vis, elemental analysis, mass spectra and X-ray single crystal diffraction. [Pt(heineo)(2)] was obtained as a single crystal, while [Pd(heineo)(2)] was synthesized as a polycrystalline powder. The X-ray diffraction analysis of the [Pt(heineo)2] indicated that the platinum(II) ion is coordinated by two heineo ligands in a distorted square-planar geometry. DFT (B3LYP/6-311++G(d,p) and LANL2DZ) calculations on the ligand and its complexes were carried out to correlate the geometry and vibrational and electronic properties. Additionally, heineoH is fluorescent in EtOH at room temperature, but the fluorescence is quenched in the case of the metal complexes. (C) 2014 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessCrystal structurePlatinum(II)DFT calculationsImineoximeFluorescencePalladium(II)Crystal structureX ray diffraction analysisElectronic propertiesPlatinumFluorescencePalladium compoundsGeometryNaphthaleneLigandsMetal complexesMass spectrometryDensity-functional theoryCrystal-structureChemistryVibrational analysisSequencesMacrocyclic complexNickel(ii)Td-dftSpectraOximeDft calculation.Polycrystalline powdersX-ray single-crystal diffractionSpectroscopic propertyTheoretical investigationsSquare planar geometryStructural characterizationSynthesis (chemical)SpectroscopyCoordination complexesCrystallography, x-rayIminesMagnetic resonance spectroscopyMass spectrometryModels, molecularOrganoplatinum compoundsOximesPalladiumSpectrophotometry, ultravioletA combined experimental and theoretical investigation of a new imineoxime and its palladium(II) and platinum(II) complexes: Synthesis, structural characterization and spectroscopic propertiesArticle0003403309000152-s2.0-849025059669310113324929321SpectroscopyIsonitrosoacetophenone; Oximes; AcetaldoximeChemical structureChemistryMass spectrometryNuclear magnetic resonance spectroscopySynthesisUltraviolet spectrophotometryX ray crystallographyCoordination compoundImineOximePalladiumPlatinum complex