Kazak, Canan2021-11-102021-11-102010-03-10Güney, E. vd. (2010). "Bis(saccharinato)palladium(II) and platinum(II) complexes with 2,2 '-bipyridine: Syntheses, structures, spectroscopic, fluorescent and thermal properties". Polyhedron, 29(4), 1285-1290.0277-5387https://doi.org/10.1016/j.poly.2010.01.006https://www.sciencedirect.com/science/article/pii/S0277538710000215http://hdl.handle.net/11452/22602New palladium(II) and platinum(II) complexes, cis-[Pd(bpy)(sac)(2)] (1) and cis-[Pt(bpy)(sac)(2)] (2), where sac = saccharinate, bpy = 2,2'-bipyridine, have been synthesized and characterized by elemental analysis, UV-Vis, IR, H-1 NMR and C-13 NMR. The structures of the DMSO solvated complexes are determined by X-ray diffraction. Both complexes are isomorphous and the metal ions are coordinated by two N-bonded sac ligands, and two nitrogen atoms of pyridyl groups of bpy in a cis fashion. The mononuclear species interact each other through weak intermolecular C-H center dot center dot center dot O hydrogen bonds, C-H center dot center dot center dot pi and pi-pi interactions leading to three-dimensional supramolecular networks. All complexes exhibit a high thermal stability in the solid state, and are fluorescent in the solution.eninfo:eu-repo/semantics/closedAccessSaccharinate2,2 '-BipyridinePalladium(II)Platinum(II)Crystal structureX-ray-structureCrystal-structurePalladium(II) complexesDNA-bindingSaccharinate complexesElectronic-structureAlpha-diimineRed formLigands2,2-bipyridylChemistryCrystallographyArticle0002760009000132-s2.0-7674915487312851290294Chemistry, inorganic & nuclearCrystallographyBenzisothiazole; Palladium; 2-Phenylpyridine