Akhbari, KamranBeheshti, SaeidehMorsali, AliBüyükgüngör, Orhan2022-09-092022-09-092014-09-25Akhbari, K. vd. (2014). "Holodirected coordination sphere around lead(II) in three-dimensional polymeric structure; New precursor for preparation of lead oxide sulfate nano-structures". Journal of Molecular Structure, 1074, 279-283.0022-28601872-8014https://doi.org/10.1016/j.molstruc.2014.06.004https://www.sciencedirect.com/science/article/pii/S0022286014006000http://hdl.handle.net/11452/28619A new lead(II) three-dimensional coordination polymer, [Pb-2(mu(3)-ANS)(2)(mu(2)-Cl)(2)(H2O)(2)](n) (1) [ANS(-) = 4-amino-1 -naphthalenesulfonateb has been synthesized and characterized. The single-crystal X-ray data of compound 1 shows only one type of Pb-II ion with coordination number of six, the lead atom has distorted octahedral coordination sphere containing stereo-chemically inactive electron lone pair. The thermal stability of 1 was studied by TG-DTA (Thermo gravimetric and differential thermal analyses). Regular morphology of Pb-2(SO4)O nano-particle was prepared from fine powders of compound 1 by calcination process at 700 degrees C. This nano-structure was characterized by XRD (X-ray powder diffraction) and SEM (Scanning electron microscopy).eninfo:eu-repo/semantics/closedAccessLead(II)Coordination polymerHolodirectedLead oxide sulfateNano-particleDesignRoomChemistryDifferential thermal analysisLeadLead oxideNanoparticlesScanning electron microscopyX ray powder diffractionCoordination numberCoordination polymersCoordination sphereElectron lone pairHolodirectedOctahedral coordinationPolymeric structuresThermo-gravimetricPolymersArticle0003403152000352-s2.0-849037449292792831074Chemistry, physicalCoordination Polymer; X-Ray Powder Diffraction; Elemental Analyses